440655
Boc-Asp(OBzl)-OH
98%
别名:
N-(叔丁氧羰基)-L-天冬氨酸-4-苄酯, Boc-L-天冬氨酸-4-苄酯
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关于此项目
线性分子式:
C6H5CH2OCOCH2CH(COOH)NHCOOC(CH3)3
化学文摘社编号:
分子量:
323.34
EC Number:
231-406-8
UNSPSC Code:
12352200
PubChem Substance ID:
Beilstein/REAXYS Number:
2064127
MDL number:
InChI key
SOHLZANWVLCPHK-LBPRGKRZSA-N
InChI
1S/C16H21NO6/c1-16(2,3)23-15(21)17-12(14(19)20)9-13(18)22-10-11-7-5-4-6-8-11/h4-8,12H,9-10H2,1-3H3,(H,17,21)(H,19,20)/t12-/m0/s1
SMILES string
[H][C@@](CC(=O)OCc1ccccc1)(NC(=O)OC(C)(C)C)C(O)=O
assay
98%
optical activity
[α]20/D −19.5°, c = 2 in DMF
mp
98-102 °C (lit.)
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Application
用于光学异构合成 (R)-(+)-Boc-iturinic acid (n-C14)、L-天冬氨酸系列凝血酶抑制剂，以及二酮哌嗪四肽的原料。用于制备位于 [6H]-氮杂卓并吲哚啉中心的新型模拟三环二肽。
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Bergeron, R.J. et al.
Journal of the American Chemical Society, 116, 8479-8479 (1994)
K Hilpert et al.
Journal of medicinal chemistry, 37(23), 3889-3901 (1994-11-11)
Thrombin, a serine protease, plays a central role in the initiation and propagation of thrombotic events. An extensive search for new thrombin inhibitors was performed, using an unconventional approach. Screening of small basic molecules for binding in the recognition pocket
Bland, J.M.
Synthetic Communications, 25, 467-467 (1995)
De Lombaert, S. et al.
Tetrahedron Letters, 35, 7513-7513 (1994)
Nicole Niklas et al.
Dalton transactions (Cambridge, England : 2003), (1)(1), 154-162 (2006-12-13)
The amino acid derivative Boc-Asp-OBzl (Boc=N-butyloxycarbonyl; Asp=aspartic acid; Bzl=benzyl) was functionalized by coupling its carboxylate side chain to dipicolylamine. This yielded the tridentate nitrogen donor ligand Boc-Asp(Dpa)-OBzl (-OBzl). The compound -OBzl contains three different carbonyl groups: a tertiary amide linkage
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