448427
(4R)-2-羟基-5,5-二甲基-4-苯基-1,3,2-二噁磷己环 2-氧化物
98%
别名:
(2R,4R)-5,5-二甲基-2-羟基-4-苯基-1,3,2-二氧磷杂环己烷 2-氧化物, (R)-(-)-2-羟基-5,5-二甲基-4-苯基-1,3,2-二氧磷杂环己烷 2-氧化物
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关于此项目
经验公式（希尔记法）:
C11H15O4P
化学文摘社编号:
分子量:
242.21
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4294714
产品名称
(4R)-2-羟基-5,5-二甲基-4-苯基-1,3,2-二噁磷己环 2-氧化物, 98%
InChI
1S/C11H15O4P/c1-11(2)8-14-16(12,13)15-10(11)9-6-4-3-5-7-9/h3-7,10H,8H2,1-2H3,(H,12,13)/t10-/m1/s1
SMILES string
CC1(C)COP(O)(=O)O[C@@H]1c2ccccc2
InChI key
PSZSDCWNBXVDFG-SNVBAGLBSA-N
assay
98%
optical activity
[α]20/D −62°, c = 0.5 in methanol
impurities
<5% water
mp
224-227 °C (lit.)
functional group
phenyl
phosphate
storage temp.
2-8°C
Quality Level
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Application
(4R)-2-Hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide can be used:
- As a reactant in the phosphoalkoxylation of aromatic enones.
- As a chiral resolving agent in the resolution of amino acids, amines, and amino alcohols.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Enantiomeric impurities in chiral catalysts, auxiliaries and synthons used in enantioselective synthesis
Armstrong DW, et al.
Tetrahedron Asymmetry, 9(12), 2043-2064 (1998)
Four-component α-bromo-β-phosphoalkoxylation of aromatic α, β-unsaturated carbonyl compounds
Sohail M, et al.
Royal Society of Chemistry Advances, 5(22), 17014-17017 (2015)
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