448427
(4R)-2-羟基-5,5-二甲基-4-苯基-1,3,2-二噁磷己环 2-氧化物
98%
别名:
(2R,4R)-5,5-二甲基-2-羟基-4-苯基-1,3,2-二氧磷杂环己烷 2-氧化物, (R)-(-)-2-羟基-5,5-二甲基-4-苯基-1,3,2-二氧磷杂环己烷 2-氧化物
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关于此项目
经验公式（希尔记法）:
C11H15O4P
化学文摘社编号:
分子量:
242.21
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4294714
产品名称
(4R)-2-羟基-5,5-二甲基-4-苯基-1,3,2-二噁磷己环 2-氧化物, 98%
InChI
1S/C11H15O4P/c1-11(2)8-14-16(12,13)15-10(11)9-6-4-3-5-7-9/h3-7,10H,8H2,1-2H3,(H,12,13)/t10-/m1/s1
SMILES string
CC1(C)COP(O)(=O)O[C@@H]1c2ccccc2
InChI key
PSZSDCWNBXVDFG-SNVBAGLBSA-N
assay
98%
optical activity
[α]20/D −62°, c = 0.5 in methanol
impurities
<5% water
mp
224-227 °C (lit.)
functional group
phenyl
phosphate
storage temp.
2-8°C
Quality Level
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Application
(4R)-2-Hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide can be used:
- As a reactant in the phosphoalkoxylation of aromatic enones.
- As a chiral resolving agent in the resolution of amino acids, amines, and amino alcohols.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Four-component α-bromo-β-phosphoalkoxylation of aromatic α, β-unsaturated carbonyl compounds
Sohail M, et al.
Royal Society of Chemistry Advances, 5(22), 17014-17017 (2015)
Enantiomeric impurities in chiral catalysts, auxiliaries and synthons used in enantioselective synthesis
Armstrong DW, et al.
Tetrahedron Asymmetry, 9(12), 2043-2064 (1998)
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