450898
三氯化镓
anhydrous, beads, −10 mesh, 99.99% trace metals basis
别名:
氯化镓
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关于此项目
线性分子式:
GaCl3
化学文摘社编号:
分子量:
176.08
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23
等级
anhydrous
蒸汽压
1 mmHg ( 48 °C)
方案
99.99% trace metals basis
表单
beads
反应适用性
reagent type: catalyst
core: gallium
杂质
≤150.0 ppm Trace Metal Analysis
粒径
−10 mesh
mp
78 °C (lit.)
密度
2.47 g/mL at 25 °C (lit.)
SMILES字符串
Cl[Ga](Cl)Cl
InChI
1S/3ClH.Ga/h3*1H;/q;;;+3/p-3
InChI key
UPWPDUACHOATKO-UHFFFAOYSA-K
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应用
用于许多转化反应（例如环氧化物的开环和再环合反应，或者炔烃的三聚反应）的催化剂。
特点和优势
使用 GaCl3 和 NaN3 或 Li3N 的低温溶剂热技术可产生纳米晶 GaN。
许多有机键形成反应中的自由基介质和催化剂。
包装
样品瓶包装
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
补充剂危害
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Barman, D.C.
Synlett, 2440-2440 (2003)
C Caraco et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 49(12), 1477-1479 (1998-09-24)
Previous studies report that deferoxamine (DFO) binds metallic ions such as Fe3+, In3+ and Ga3+ with very high affinity. This property of DFO has been utilized to label DFO-coupled compounds with radiometals such as 67Ga and 111In. We have studied
Han-Gook Cho
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 59(7), 1517-1528 (2003-04-26)
Remarkably large blue shifts of the nu2 C [triple bond] N stretch, nu4 C-C stretch, and nu8 CCN deformation bands of CD3CN are observed in the infrared and Raman spectra of CD3CN solution of GaCl3, resulting from the donor-acceptor interaction
Amir R Jalilian et al.
Acta pharmaceutica (Zagreb, Croatia), 59(4), 421-429 (2009-11-19)
beta-Human chorionic gonadotropin (beta-hCG) was successively labeled with [(67)Ga]-gallium chloride after conjugation with freshly prepared diethylenetriaminepentaacetic acid dianhydride (ccDTPA). After solid phase purification of the radiolabeled hormone, high performance liquid chromatography showed radiochemical purity higher than 95 % under optimized
Tiina Ujula et al.
Molecular imaging and biology : MIB : the official publication of the Academy of Molecular Imaging, 12(3), 259-268 (2009-10-03)
The aim of the study was to compare (68)Ga-chloride with 2-[(18)F]fluoro-2-deoxy-D: -glucose (FDG) for the imaging of pancreatic xenografts. Rats with subcutaneous human pancreatic adenocarcinoma xenografts were evaluated in vivo by dynamic positron emission tomography (PET) and ex vivo by
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