453455
三苯甲基-(R)-缩水甘油醚
98%, optical purity ee: 98% (GLC)
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关于此项目
经验公式（希尔记法）:
C22H20O2
化学文摘社编号:
分子量:
316.39
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
assay
98%
form
solid
optical activity
[α]20/D +10.5°, c = 1 in chloroform
optical purity
ee: 98% (GLC)
mp
99-102 °C (lit.)
SMILES string
C1O[C@H]1COC(c2ccccc2)(c3ccccc3)c4ccccc4
InChI
1S/C22H20O2/c1-4-10-18(11-5-1)22(24-17-21-16-23-21,19-12-6-2-7-13-19)20-14-8-3-9-15-20/h1-15,21H,16-17H2/t21-/m1/s1
InChI key
XFSXUCMYFWZRAF-OAQYLSRUSA-N
Application
(R)-(+)-Glycidyl trityl ether may be used in the preparation of (R)-trityl(thiiranylmethyl)ether by reacting with thiourea. It may also be used as a starting material in the multi-step synthesis of (+)-actisonitrile.
近期已通过分别用胞嘧啶衍生物、胺和硫醇使该环氧化物开环，制备具有抗单纯疱疹病毒 1 和 2 活性的核苷酸、铵盐脂质体以及磷脂的硫代类似物。
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Synthesis of aminoethanethiol trityl ether ligands for ruthenium-catalysed asymmetric transfer hydrogenation.
Harfouche J, et al.
Tetrahedron Letters, 15(21), 3413-3418 (2004)
Bennett, M.J. et al.
Tetrahedron Letters, 36, 2207-2207 (1995)
Brodfuehrer, P.R. et al.
Tetrahedron Letters, 35, 3243-3243 (1994)