456411
十二氯三钛铝
TiCl3:AlCl3 3:1
别名:
三氯化钛-三氯化铝混合体
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关于此项目
线性分子式:
(TiCl3)3 · AlCl3
化学文摘社编号:
分子量:
596.02
UNSPSC Code:
12352106
PubChem Substance ID:
EC Number:
234-421-8
MDL number:
form
solid
composition
TiCl3:AlCl3, 3:1
reaction suitability
reagent type: catalyst
core: titanium
SMILES string
Cl[Al](Cl)Cl.Cl[Ti](Cl)Cl.Cl[Ti](Cl)Cl.Cl[Ti](Cl)Cl
InChI
1S/Al.12ClH.3Ti/h;12*1H;;;/q+3;;;;;;;;;;;;;3*+3/p-12
InChI key
DGFMFXMKCUOBCD-UHFFFAOYSA-B
Application
低价钛在咪唑啉合成中是一种有用的还原剂。
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Pyr. Sol. 1 - Skin Corr. 1B
supp_hazards
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Atul A More et al.
Organic letters, 18(6), 1458-1461 (2016-03-08)
The first total synthesis of integrastatin B, a potent HIV-1 integrase inhibitor, has been accomplished in seven steps with a 17.9% overall yield employing easily accessible starting compounds. The Oxone-mediated oxidative benzofuran dearomatization cascade has been employed as the key
Periasamy, M. et al.
Tetrahedron Letters, 37, 4767-4767 (1996)