主要文件

查看所有文档

457701

(S)-(-)-2-甲基-CBS-噁唑硼烷溶液

Name: (<I>S</I>)-(-)-2-甲基-CBS-噁唑硼烷 溶液
Brand: ALDRICH

1 M in toluene

别名:

α,α-二苯基-L-脯氨醇甲基硼酸环胺酯, (S)-1-甲基-3,3-二苯基-四氢-吡咯并[1,2c][1,3,2]噁唑硼烷, (S)-3,3-二苯基-1-甲基四氢-3H-吡咯并[1,2-c][1,3,2]噁唑硼烷, (S)-四氢-1-甲基-3,3-二苯基-1H,3H-吡咯并[1,2-c][1,3,2]噁唑硼烷

登录查看组织和合同定价。

选择尺寸

变更视图

关于此项目

经验公式（希尔记法）:

C₁₈H₂₀BNO

化学文摘社编号:

112022-81-8

分子量:

277.17

NACRES:

NA.22

PubChem Substance ID:

24869386

UNSPSC Code:

12352005

MDL number:

MFCD00078439

技术服务

需要帮助？我们经验丰富的科学家团队随时乐意为您服务。

让我们为您提供帮助

属性

Quality Level

100

concentration

1 M in toluene

bp

111 °C

density

0.929 g/mL at 25 °C

functional group

phenyl

storage temp.

room temp

SMILES string

CB1OC([C@@H]2CCCN12)(c3ccccc3)c4ccccc4

InChI

1S/C18H20BNO/c1-19-20-14-8-13-17(20)18(21-19,15-9-4-2-5-10-15)16-11-6-3-7-12-16/h2-7,9-12,17H,8,13-14H2,1H3/t17-/m0/s1

InChI key

VMKAFJQFKBASMU-KRWDZBQOSA-N

说明

Application

CBS (Corey-Bakshi-Shibata) 噁唑硼烷催化剂已被用于前手性酮的非对称性还原。其他应用包括 α-羟基酸、α-氨基酸、C₂ 对称二茂铁二醇以及炔丙醇的对映选择性合成。

用于 (S)-2-氨基-1-苯乙醇的对映选择性合成的催化剂。

用于非对称性还原反应的优良催化剂。

(S)-(-)-2-Methyl-CBS-oxazaborolidine solution [1M in toluene] may be used as a catalyst in the multi-step synthesis of (-)-diospongin A.
It may also be used in the preparation of:

(1S)-2-azido-1-(2,2-dimethyl-4H-1,3-benzodioxin-6-yl)ethanol
(R)-α-deuteriobenzyl alcohol
(R)-2-(1-hydroxyethyl)benzo[b]thiophene

用于不对称还原和不对称合成的CBS催化剂

Other Notes

储存时可能形成沉淀，但不影响产品质量。在惰性气体环境下将产品缓慢加热至 80-90°C，使固体再溶解。

Still not finding the right product?

Explore all of our products under (S)-(-)-2-甲基-CBS-噁唑硼烷溶液

pictograms

GHS02,GHS08,GHS05,GHS07

signalword

Danger

hcodes

H225,H302,H304,H315,H318,H336,H361d,H373,H412

pcodes

P201 - P210 - P273 - P280 - P301 + P310 + P331 - P305 + P351 + P338 + P310

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

target_organs

Central nervous system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

39.2 °F - closed cup

flash_point_c

4 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

新产品

此项目有

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

没有发现合适的版本？

如果您需要特殊版本，可通过批号或批次号查找具体证书。

搜索COA

已有该产品？

在文件库中查找您最近购买产品的文档。

访问文档库

商品

CBS Catalysts

we are pleased to offer both enatiomers of 2-methyl-CBS-oxazaborolidine as a dry reagent, in addition to our current offerings as a 1M solution in toluene.

Asymmetric Catalysis with Chiral Oxazaborolidinium Ions (COBIs)

Learn about the applications of chiral oxazaborolidinium ions (COBIs) as Lewis acid catalysts in different asymmetric reactions such as cyclopropanation, epoxidation, and radical reactions along with details of their catalytic action.

Enantioselective synthesis of (S)-salmeterol via asymmetric reduction of azidoketone by Pichia angusta.

Procopiou PA, et al.

Tetrahedron Asymmetry, 12(14), 2005-2008 (2001)

Organic Process Research & Development, 10, 893-893 (2006)

Diastereoselective photochromism of a bisbenzothienylethene governed by steric as well as electronic interactions.

Yokoyama Y, et al.

Journal of the American Chemical Society, 125(24), 7194-7195 (2003)

查看所有相关文献

全球贸易项目编号

货号	GTIN
457701-25ML	04061838127914
457701-5ML	04061838127921

主要文件

(S)-(-)-2-甲基-CBS-噁唑硼烷溶液

1 M in toluene