458856
N-(叔丁氧基羰基)-L-脯氨酸-N′-甲氧基-N′-甲酰胺
98%
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关于此项目
经验公式（希尔记法）:
C12H22N2O4
化学文摘社编号:
分子量:
258.31
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352209
MDL number:
InChI
1S/C12H22N2O4/c1-12(2,3)18-11(16)14-8-6-7-9(14)10(15)13(4)17-5/h9H,6-8H2,1-5H3/t9-/m0/s1
SMILES string
CON(C)C(=O)[C@@H]1CCCN1C(=O)OC(C)(C)C
InChI key
KPVRHJIGNMLCHG-VIFPVBQESA-N
assay
98%
optical activity
[α]22/D −38°, c = 1 in methanol
reaction suitability
reaction type: solution phase peptide synthesis
refractive index
n20/D 1.471 (lit.)
bp
253 °C (lit.)
density
1.059 g/mL at 25 °C (lit.)
application(s)
peptide synthesis
Application
α-氨基 Weinreb 酰胺。
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
Lucet, D. et al.
Tetrahedron Asymmetry, 7, 985-985 (1996)
Kosynkina, L. et al.
Tetrahedron Letters, 35, 5173-5173 (1994)
Kim, B.M. et al.
Tetrahedron Letters, 35, 5153-5153 (1994)
Saari, W.S. Fischer, T.E.
Synthesis, 453-453 (1990)
Angelastro, M.R. at al.
Tetrahedron Letters, 33, 3265-3265 (1992)
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