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Merck
CN

459992

Sigma-Aldrich

foil, thickness 0.5 mm, 99% trace metals basis

别名:

Glucinium

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关于此项目

经验公式(希尔记法):
Be
化学文摘社编号:
分子量:
9.01
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
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方案

99% trace metals basis

表单

foil

自燃温度

1198 °F

反应适用性

reagent type: catalyst
core: beryllium

电阻率

4.46 μΩ-cm, 20°C

厚度

0.5 mm

沸点

2970 °C (lit.)

mp

1278 °C (lit.)

密度

1.85 g/mL at 25 °C (lit.)

SMILES字符串

[Be]

InChI

1S/Be

InChI key

ATBAMAFKBVZNFJ-UHFFFAOYSA-N

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应用

Reagent for synthesis of:
  • Beryllium phthalocyanine and its derivatives
  • Catalyst with cerium oxide for oxidative coupling of methane
  • Organoberyllium compounds

Reagent for:
  • Metal mediated dechlorination
  • Stereoselective Horner-Wadsworth-Emmons reactions

制备说明

525mg = 25×25mm

象形图

Skull and crossbonesHealth hazard

警示用语:

Danger

危险分类

Acute Tox. 3 Oral - Carc. 1B - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1

储存分类代码

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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David D Díaz et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(9), 2593-2606 (2006-01-10)
A highly regio- and stereoselective intramolecular [1,5]-hydrogen-transfer process is described. Treatment of gamma-benzyl-protected Co2(CO)6-alpha,gamma-acetylenic diols with BF3 x OEt2 provides bis-homopropargylic alcohols. The reaction occurs within seconds, tolerates a wide range of functionalities, and provides good yields. When the ether
I. I. Lapkin and S. V. Sinani,
Zh. Obshch. Khim., 57, 372-375 (1987)
K. Otsuka, et al.,
Chemistry Letters (Jpn), 9, 1835-1838 (1987)
V. K. Tandon and R. B. Chhor,
Letters in Organic Chemistry, 1, 40-42 (2004)
Shengli Zhu et al.
Journal of the mechanical behavior of biomedical materials, 13, 166-173 (2012-08-18)
We developed Ni- and Be-free Zr(45+x)Cu(40-x)Al₇Pd₅Nb₃ bulk metallic glasses with large glass-forming ability and unusual plasticity. The alloys have large critical diameters (larger than 10 mm) in a wide composition range (x=0-20). The Zr₅₀Cu₃₅Al₇Pd₅Nb₃ and Zr₅₅Cu₃₀Al₇Pd₅Nb₃ alloys exhibit the largest

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