461075
1-三甲基硅基吡咯酮
96%
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关于此项目
经验公式(希尔记法):
C7H15NOSi
化学文摘社编号:
分子量:
157.29
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
方案
96%
折射率
n20/D 1.46 (lit.)
沸点
90 °C/20 mmHg (lit.)
密度
0.983 g/mL at 25 °C (lit.)
SMILES字符串
C[Si](C)(C)N1CCCC1=O
InChI
1S/C7H15NOSi/c1-10(2,3)8-6-4-5-7(8)9/h4-6H2,1-3H3
InChI key
LUBVCBITQHEVCJ-UHFFFAOYSA-N
一般描述
1-(Trimethylsilyl)-2-pyrrolidinone has been prepared by refluxing a mixture of 2-pyrrolidinone, triethylamine and trimethylchlorosilane in benzene. It undergoes sulfenylation with phenyl disulfide to form the corresponding bissulfide as the major product.
应用
1-(Trimethylsilyl)-2-pyrrolidinone may be used for the preparation of 1-(diphenylphosphonio)pyrrolidin-2-one and 1-(1-adamantylcarbonyl)-2-pyrrolidinone.
警示用语:
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
127.4 °F - closed cup
闪点(°C)
53 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Synthesis and antiviral activity evaluation of some new aminoadamantane derivatives. 2.
Kolocouris N, et al.
Journal of Medicinal Chemistry, 39(17), 3307-3318 (1996)
Synthesis, conformational characteristics and anti-influenza virus A activity of some 2-adamantylsubstituted azacycles.
Setaki D, et al.
Bioorganic Chemistry, 34(5), 248-273 (2006)
Sulfenylation and sulfinylation of lactams and imino ethers.
Zoretic PA, et al.
The Journal of Organic Chemistry, 43(7), 1379-1382 (1978)
Efficient method for the preparation of carboxylic acid alkyl esters or alkyl phenyl ethers by a new-type of oxidation-reduction condensation using 2, 6-dimethyl-1, 4-benzoquinone and alkoxydiphenylphosphines.
Shintou T, et al.
Bulletin of the Chemical Society of Japan, 76(8), 1645-1667 (2003)
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