产品名称
2-苯甲酰环己酮, 98%
InChI
1S/C13H14O2/c14-12-9-5-4-8-11(12)13(15)10-6-2-1-3-7-10/h1-3,6-7,11H,4-5,8-9H2
SMILES string
O=C1CCCCC1C(=O)c2ccccc2
InChI key
YTVQIZRDLKWECQ-UHFFFAOYSA-N
assay
98%
form
solid
mp
88-91 °C (lit.)
functional group
ketone
phenyl
General description
2-Benzoylcyclohexanone can be prepared from the reaction between silyl enol ether of cyclohexanone and benzoyl fluoride.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
The regioselective preparation of 1, 3-diketones within a micro reactor.
Wiles C, et al.
Chemical Communications (Cambridge, England), 10, 1034-1035 (2002)
Gilbert E Tumambac et al.
Chirality, 17(4), 171-176 (2005-04-13)
The kinetics of the racemization of 2-benzoylcyclohexanone 1 in hexanes, ethanol, and mixtures thereof have been investigated by time dependence of enantiomeric purity using enantioselective HPLC. In pure hexanes and ethanol, the racemization half-lives were determined as 552 and 23.8
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