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Merck
CN

463671

氟氢化钾

≥99.99%

别名:

二氟氢化钾, 二氟氢钾

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关于此项目

线性分子式:
KHF2
化学文摘社编号:
分子量:
78.10
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
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方案

≥99.99%

mp

239 °C (lit.)

密度

2.37 g/mL at 25 °C (lit.)

SMILES字符串

[F-].[K+].F[H]

InChI

1S/2FH.K/h2*1H;/q;;+1/p-1

InChI key

VBKNTGMWIPUCRF-UHFFFAOYSA-M

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应用

用于不饱和化合物的氢氟化。

象形图

Skull and crossbonesCorrosion

警示用语:

Danger

危险声明

危险分类

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B

储存分类代码

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges

法规信息

新产品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Journal of the Chemical Society. Chemical Communications, 1891-1891 (1995)
Gary A Molander et al.
The Journal of organic chemistry, 73(17), 6841-6844 (2008-08-07)
A number of alkynyl pinacolboronates bearing various functional groups were synthesized according to literature methods. These were then stereoselectively reduced to the cis-alkenyl pinacolboronates via hydroboration with dicyclohexylborane followed by chemoselective protodeboronation using acetic acid. Treatment with potassium hydrogen fluoride
Reaction of 2-deoxy-6-O-[2,3-dideoxy-4,6-O-isopropylidene-2,3- (N-tosylepimino)-alpha-D-mannopyranosyl]-4,5-O-isopropylidene-1,3-di-N- tosylstreptamine with potassium hydrogenfluoride.
Y Kobayashi et al.
Carbohydrate research, 229(2), 363-368 (1992-05-22)
Matthew J Hesse et al.
Angewandte Chemie (International ed. in English), 51(50), 12444-12448 (2012-11-07)
E-allylic boronic esters undergo a highly diastereoselective protodeboronation with TBAF⋅3 H(2)O to give Z-trisubstituted alkenes. The selectivity can be switched to give predominantly the E-alkene instead by using KHF(2)/TsOH (see scheme). The utility of the methodology has been illustrated in a
Hoang-Duy Nguyen et al.
Angewandte Chemie (International ed. in English), 54(37), 10862-10866 (2015-07-28)
A facile approach for coating red fluoride phosphors with a moisture-resistant alkyl phosphate layer with a thickness of 50-100 nm is reported. K2 SiF6 :Mn(4+) particles were prepared by co-precipitation and then coated by esterification of P2 O5 with alcohols (methanol

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