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Merck
CN

464058

D-葡萄烯糖

96%

别名:

D-己烯糖

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关于此项目

经验公式(希尔记法):
C6H10O4
化学文摘社编号:
分子量:
146.14
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352201
EC Number:
236-259-3
MDL number:
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产品名称

D-葡萄烯糖, 96%

InChI key

YVECGMZCTULTIS-PBXRRBTRSA-N

InChI

1S/C6H10O4/c7-3-5-6(9)4(8)1-2-10-5/h1-2,4-9H,3H2/t4-,5-,6+/m1/s1

SMILES string

OC[C@H]1OC=C[C@@H](O)[C@@H]1O

assay

96%

form

solid

optical activity

[α]21/D −7°, c = 1.9 in H2O

impurities

<1% methyl alcohol

mp

58-60 °C (lit.)

storage temp.

2-8°C

Quality Level

Application

可同时用于寡糖的溶液相和固相合成的重要结构单元。

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Xi-Kai Cui et al.
Carbohydrate research, 358, 19-22 (2012-08-03)
2-Deoxyglycosides were synthesized in high α-selectivity by the direct addition of alcohols to D-glucal and D-galactal catalyzed by TMSI and PPh(3). The acid labile isopropylidene group is tolerated under this condition.
A possible catalytic role of pyridoxal-5'-phosphate in a general acid base catalyzed reaction of D-glucal with glycogen phosphorylases.
E J Helmreich et al.
Progress in clinical and biological research, 102 Pt C, 23-35 (1982-01-01)
Syed Khalid Yousuf et al.
The Journal of organic chemistry, 75(9), 3097-3100 (2010-04-13)
Novel one-pot three- and four-component transformations of D-glucal to furan-based hydroxy triazole glycoconjugates have been achieved by sequential addition of reagents in the presence of Cu(OTf)(2)-Cu powder as catalysts. In general the carbohydrate-derived products were formed with high diastereomeric purity.
Russell J Hewitt et al.
The Journal of organic chemistry, 75(3), 955-958 (2010-01-14)
The conversion of cyclopropane-fused carbohydrates into oxepines is an attractive method for accessing diverse members of the septanoside family of carbohydrate mimetics. 2-Bromooxepines are obtained through silver(I)-promoted thermal ring expansion of a d-glucal-derived gem-dihalocyclopropanated sugar. In contrast, cyclopropane ring cleavage
Y Nagumo et al.
Bioorganic & medicinal chemistry letters, 11(15), 2037-2040 (2001-07-17)
Monoclonal antibodies (mAbs), 4H2 and 6H7, were prepared previously using a protein conjugate of a 1:1 epimeric mixture of the synthetic ABC-ring fragments of ciguatoxin (CTX), 3 and 4. Here, the interactions of these mAbs with the fragments of CTX

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