464058
D-葡萄烯糖
96%
别名:
D-己烯糖
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关于此项目
经验公式（希尔记法）:
C6H10O4
化学文摘社编号:
分子量:
146.14
EC 号:
MDL编号:
UNSPSC代码:
12352201
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
96%
表单
solid
旋光性
[α]21/D −7°, c = 1.9 in H2O
杂质
<1% methyl alcohol
mp
58-60 °C (lit.)
储存温度
2-8°C
SMILES字符串
OC[C@H]1OC=C[C@@H](O)[C@@H]1O
InChI
1S/C6H10O4/c7-3-5-6(9)4(8)1-2-10-5/h1-2,4-9H,3H2/t4-,5-,6+/m1/s1
InChI key
YVECGMZCTULTIS-PBXRRBTRSA-N
应用
可同时用于寡糖的溶液相和固相合成的重要结构单元。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
此项目有
A possible catalytic role of pyridoxal-5'-phosphate in a general acid base catalyzed reaction of D-glucal with glycogen phosphorylases.
E J Helmreich et al.
Progress in clinical and biological research, 102 Pt C, 23-35 (1982-01-01)
B Evers et al.
Bioorganic & medicinal chemistry, 5(5), 857-863 (1997-05-01)
Maltopentaose was immobilized on silica gel and used as a recyclable primer in the reaction of glycogen phosphorylase with D-glucal. An improved method to obtain 2-deoxy-alpha-D-arabino-hexopyranosyl phosphate (4) by using this catalyst as well as the specific synthesis of low
Russell J Hewitt et al.
The Journal of organic chemistry, 75(3), 955-958 (2010-01-14)
The conversion of cyclopropane-fused carbohydrates into oxepines is an attractive method for accessing diverse members of the septanoside family of carbohydrate mimetics. 2-Bromooxepines are obtained through silver(I)-promoted thermal ring expansion of a d-glucal-derived gem-dihalocyclopropanated sugar. In contrast, cyclopropane ring cleavage
Syed Khalid Yousuf et al.
The Journal of organic chemistry, 75(9), 3097-3100 (2010-04-13)
Novel one-pot three- and four-component transformations of D-glucal to furan-based hydroxy triazole glycoconjugates have been achieved by sequential addition of reagents in the presence of Cu(OTf)(2)-Cu powder as catalysts. In general the carbohydrate-derived products were formed with high diastereomeric purity.
Valeria Di Bussolo et al.
The Journal of organic chemistry, 69(25), 8702-8708 (2004-12-04)
6-O-Trityl- (1a) and 6-(O-benzyl)-substituted epoxide (1b) derived from D-glucal were examined in their addition reactions with O-, C-, N-, and S-nucleophiles. A 1,4-regio- and beta-stereoselective or an anti 1,2-addition pathway is commonly observed depending on the ability of the nucleophile
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