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467278

N-甲基-邻甲苯胺

Name: <I>N</I>-甲基-邻甲苯胺
Brand: ALDRICH

≥95%

别名:

2,N-Dimethylaniline, 2-Methyl-N-methylaniline, N,2-Dimethylaniline, N,2-Dimethylbenzenamine, N,o-Dimethylaniline, N-(2-Methylphenyl)methylamine, N-Methyl-2-methylaniline, N-Methyl-2-methylbenzenamine, N-Methyl-N-(o-tolyl)amine, N-Methyl-o-methylaniline, o,N-Dimethylaniline, Methyl(o-tolyl)amine, NSC 9395

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关于此项目

线性分子式:

CH₃C₆H₄NHCH₃

化学文摘社编号:

611-21-2

分子量:

121.18

NACRES:

NA.22

PubChem Substance ID:

24870394

UNSPSC Code:

12352100

EC Number:

210-260-9

MDL number:

MFCD00025627

Assay:

≥95%

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属性

assay

≥95%

bp

177-204 °C/740 mmHg (lit.)

density

0.981 g/mL at 25 °C (lit.)

functional group

amine

SMILES string

CNc1ccccc1C

InChI

1S/C8H11N/c1-7-5-3-4-6-8(7)9-2/h3-6,9H,1-2H3

InChI key

GUAWMXYQZKVRCW-UHFFFAOYSA-N

说明

General description

N-Methyl-o-toluidine can be synthesized by reacting o-toluidine and benzotriazole.

Application

N-Methyl-o-toluidine may be used in the preparation of 2-substituted N-methylindoles.

染料中间体

Reactant for:

Palladium-catalyzed coupling reactions
Palladium-catalyzed amination of bromoindazoles

pictograms

GHS06,GHS08

signalword

Danger

hcodes

H301 + H311 + H331,H373,H412

pcodes

P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311 - P314

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 3 - STOT RE 2

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

174.9 °F - closed cup

flash_point_c

79.4 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Separation of isomeric amines with ion mobility spectrometry.

Jaakko Laakia et al.

Talanta, 132, 889-893 (2014-12-06)

Eight selected isomeric amines were ionized using atmospheric pressure chemical ionization and atmospheric pressure photoionization producing a protonated molecule [M+H](+) for each amine. The mobility of these ions was measured by ion mobility spectrometry. The amine compound class was shown

Carbon dioxide: a reagent for the simultaneous protection of nucleophilic centers and the activation of alternative locations to electrophilic attack. XVI, A novel synthetic method for the side-chain functionalization of N-methyl-o-toluidine and for the preparation of 2-substituted N-methylindoles.

Katritzky AR, et al.

Heterocycles, 30(1), 407-414 (1990)

A Practical Synthetic Method for N-Methyl-o-Toluidine.

Katritzky AR and Akutagawa K.

Organic preparations and procedures international, 21(3), 340-341 (1989)

全球贸易项目编号

货号	GTIN
810110P-1MG	04061835189793
810122C-1MG	04061837666100
810118P-5MG	04061835185115
810118P-1MG	04061835185108
810174P-1MG	04061835190058
810195P-1MG	04061835190195
467278-25ML	04061836827014

主要文件

N-甲基-邻甲苯胺

≥95%

选择尺寸

关于此项目

assay

bp

density

functional group

SMILES string

InChI

InChI key

General description

Application

安全信息

pictograms

signalword

hcodes

pcodes

Hazard Classifications

存储类别

wgk

flash_point_f

flash_point_c

ppe

文件

分析证书(COA)

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