468479
4-戊烯酰氯
98%
别名:
4-戊烯酸氯化物
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关于此项目
线性分子式:
H2C=CHCH2CH2COCl
化学文摘社编号:
分子量:
118.56
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
4-戊烯酰氯, 98%
InChI
1S/C5H7ClO/c1-2-3-4-5(6)7/h2H,1,3-4H2
SMILES string
ClC(=O)CCC=C
InChI key
JDKQTIKEGOOXTJ-UHFFFAOYSA-N
assay
98%
bp
125 °C (lit.)
density
1.074 g/mL at 25 °C (lit.)
functional group
acyl chloride
allyl
Quality Level
Application
4-戊烯酰氯可用于制备：
- D -pro- L 衍生环肽
- 4-戊烯酰钴三羰基
- N -4-戊烯酰- L -半胱氨酸甲酯
General description
4-戊烯酰氯已鉴别为 5-氯戊酰氯 (5-CVC) 中的关键杂质。4-戊烯酰氯可由亚硫酰氯和 4-戊烯酸反应合成。
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 3 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
80.6 °F - closed cup
flash_point_c
27 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
I Nageshwara Rao et al.
The Journal of organic chemistry, 69(6), 2181-2184 (2004-04-03)
An acyclic tripeptide based on a heterochiral D-pro-L-pro template shows a propensity to exist as a 3(10) helical conformation and can be cyclized, via ring-closing metathesis, to the corresponding cyclic tetrapeptides without disrupting the helical conformations in CDCl(3) as well
Alkyl-and Acyl-cobalt Carbonyls Containing Olefinic Unsaturation. Allylcobalt Tricarbonyl and Related Compounds1.
Heck RF and Breslow DS.
Journal of the American Chemical Society, 83(5), 1097-1102 (1961)
Synthesis and radical polyaddition of optically active monomers derived from cysteine.
Kudo H, et al.
Macromolecules, 32(25), 8370-8375 (1999)
Liya Tang et al.
Journal of pharmaceutical and biomedical analysis, 53(3), 309-314 (2010-05-05)
5-Chlorovaleroyl chloride (5-CVC) is commonly used as an alkylating agent in the synthesis of pharmaceutical intermediates, active ingredients, as well as other specialty chemicals. It is critical to monitor the impurities present in 5-CVC as they may have a direct
Norlaily Ahmad et al.
Biomacromolecules, 20(7), 2506-2514 (2019-06-28)
Inflammatory conditions are frequently accompanied by increased levels of active proteases, and there is rising interest in methods for their detection to monitor inflammation in a point of care setting. In this work, new sensor materials for disposable single-step protease
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