468517
3,5-双(三氟甲基)苯基异硫氰酸酯
98%
别名:
1-异硫氰酸基-3,5-双（三氟甲基）苯
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线性分子式:
(CF3)2C6H3NCS
化学文摘社编号:
分子量:
271.18
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
3,5-双(三氟甲基)苯基异硫氰酸酯, 98%
InChI
1S/C9H3F6NS/c10-8(11,12)5-1-6(9(13,14)15)3-7(2-5)16-4-17/h1-3H
SMILES string
FC(F)(F)c1cc(cc(c1)C(F)(F)F)N=C=S
InChI key
FXOSSGVJGGNASE-UHFFFAOYSA-N
assay
98%
refractive index
n20/D 1.5 (lit.)
bp
63 °C/1.5 mmHg (lit.)
density
1.485 g/mL at 25 °C (lit.)
functional group
fluoro
isothiocyanate
Quality Level
Application
3,5-双（三氟甲基）苯基异硫氰酸酯已用于以下研究：
- 氨基官能化模型表面的化学衍生化，金上的氨基硫醇盐，硅上的氨基硅氧烷，以及聚乙烯（PE）箔和膜。
- ω-氨基-4,4′-三联苯基取代的链烷硫醇的自组装单层的化学衍生化。
- 乙烯基磺酰亚胺硫脲的合成。
- 吡咯烷-2-羧酸-{2- [3-（3,5-双三氟甲基苯基）硫脲基]苯基}-酰胺的制备。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
228.2 °F - closed cup
flash_point_c
109 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Paul M Dietrich et al.
Langmuir : the ACS journal of surfaces and colloids, 26(6), 3949-3954 (2010-01-01)
Amino-terminated self-assembled monolayers on gold substrates were studied by X-ray photoelectron spectroscopy (XPS), near-edge X-ray absorption fine structure (NEXAFS) measurements, and atomic force microscopy (AFM). Two different omega-amino-4,4'-terphenyl substituted alkanethiols of the general structure H(2)N-(C(6)H(4))(3)-(CH(2))(n)-SH (ATPn) were used: 2-(4''-amino-1,1':4',1''-terphenyl-4-yl)ethane-1-thiol (n
Highly diastereo-and enantioselective direct aldol reactions promoted by water-compatible organocatalysts bearing a pyrrolidinyl-camphor structural scaffold.
Tzeng Z-H, et al.
Tetrahedron, 65(5), 2879-2888 (2009)
Synthesis of chiral sulfoximine-based thioureas and their application in asymmetric organocatalysis.
Marcus Frings et al.
Beilstein journal of organic chemistry, 8, 1443-1451 (2012-09-29)
For the first time, chiral sulfoximine derivatives have been applied as asymmetric organocatalysts. In combination with a thiourea-type backbone the sulfonimidoyl moiety leads to organocatalysts showing good reactivity in the catalytic desymmetrization of a cyclic meso-anhydride and moderate enantioselectivity in
Nora Graf et al.
Analytical and bioanalytical chemistry, 396(2), 725-738 (2009-11-06)
The determination of amino groups on surfaces capable of binding biomolecules is important for the understanding and optimization of technologically relevant coupling processes. In this study, three different types of amino-functionalized model surfaces, amino thiolate on Au, amino siloxane on
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