form
solid
optical activity
[α]20/D −165°, c = 1 in chloroform
reaction suitability
reaction type: Asymmetric synthesis, reaction type: C-H Activation, reagent type: catalyst
reaction type: Cyclopropanations
mp
195-200 °C (lit.)
storage temp.
2-8°C
Application
不对称环丙烷化反应的催化剂。
催化剂涉及：
- 重氮芳香基和苯乙烯基乙酸酯的立体选择性反应
- 对映选择性 C-H 卡宾插入
- 芳基炔的不对称环丙烯化
- 分子间 C-H 烯化
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Davies, H.M.L. Hutcheson, D.K.
Tetrahedron Letters, 34, 7243-7243 (1993)
Davies, H.M.L. et al.
Tetrahedron Letters, 38, 1741-1741 (1997)
Davies, H.M.L. et al.
Tetrahedron Letters, 37, 4133-4133 (1996)
Davies, H.M.L. et al.
Journal of the American Chemical Society, 118, 6897-6897 (1996)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持