472255
1,1,1-三甲基-N-(三苯基正膦亚基)硅烷胺
97%
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线性分子式:
(C6H5)3P=NSi(CH3)3
化学文摘社编号:
分子量:
349.48
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
Form:
solid
InChI
1S/C21H24NPSi/c1-24(2,3)22-23(19-13-7-4-8-14-19,20-15-9-5-10-16-20)21-17-11-6-12-18-21/h4-18H,1-3H3
SMILES string
C[Si](C)(C)N=P(c1ccccc1)(c2ccccc2)c3ccccc3
InChI key
YTKOPFGRNPVCPE-UHFFFAOYSA-N
assay
97%
form
solid
mp
76-82 °C (lit.)
functional group
phosphine
General description
1,1,1-Trimethyl-N-(triphenylphosphoranylidene)silanamine is an organic building block.
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Ranfeng Sun et al.
Organic & biomolecular chemistry, 12(31), 5954-5963 (2014-07-06)
A series of phosphinimine ligands were designed and used in the Cu(i)-catalyzed azide-alkyne cycloaddition (CuAAC) reaction of tetrazolo[1,5-a]pyridines and alkynes for the first time. By optimizing the reaction conditions, an efficient catalytic system (CuCl/2-PyCH2N[double bond, length as m-dash]P(t)Bu3) was developed
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