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472255

1,1,1-三甲基-N-(三苯基正膦亚基)硅烷胺

Name: 1,1,1-三甲基-<I>N</I>-(三苯基正膦亚基)硅烷胺
Brand: ALDRICH

97%

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关于此项目

线性分子式:

(C₆H₅)₃P=NSi(CH₃)₃

化学文摘社编号:

13892-06-3

分子量:

349.48

NACRES:

NA.22

PubChem Substance ID:

24870793

UNSPSC Code:

12352100

MDL number:

MFCD01321268

Assay:

97%

Form:

solid

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属性

assay

97%

form

solid

mp

76-82 °C (lit.)

functional group

phosphine

SMILES string

C[Si](C)(C)N=P(c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C21H24NPSi/c1-24(2,3)22-23(19-13-7-4-8-14-19,20-15-9-5-10-16-20)21-17-11-6-12-18-21/h4-18H,1-3H3

InChI key

YTKOPFGRNPVCPE-UHFFFAOYSA-N

说明

General description

1,1,1-Trimethyl-N-(triphenylphosphoranylidene)silanamine is an organic building block.

存储类别

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

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Pyridine-phosphinimine ligand-accelerated Cu(I)-catalyzed azide-alkyne cycloaddition for preparation of 1-(pyridin-2-yl)-1,2,3-triazole derivatives.

Ranfeng Sun et al.

Organic & biomolecular chemistry, 12(31), 5954-5963 (2014-07-06)

A series of phosphinimine ligands were designed and used in the Cu(i)-catalyzed azide-alkyne cycloaddition (CuAAC) reaction of tetrazolo[1,5-a]pyridines and alkynes for the first time. By optimizing the reaction conditions, an efficient catalytic system (CuCl/2-PyCH2N[double bond, length as m-dash]P(t)Bu3) was developed

全球贸易项目编号

货号	GTIN
472255-5G	04061833323755