473235
N,N-二乙基羟胺 溶液
85 wt. % in H2O
别名:
N-Hydroxydiethylamine, DEHA, Diethylhydroxylamine
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关于此项目
线性分子式:
(C2H5)2NOH
化学文摘社编号:
分子量:
89.14
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
223-055-4
MDL number:
InChI key
FVCOIAYSJZGECG-UHFFFAOYSA-N
InChI
1S/C4H11NO/c1-3-5(6)4-2/h6H,3-4H2,1-2H3
SMILES string
CCN(O)CC
concentration
85 wt. % in H2O
refractive index
n20/D 1.419
bp
125-130 °C
mp
−25 °C
density
0.902 g/mL at 25 °C
functional group
amine
General description
The product is 85wt.% solution of N,N-diethylhydroxylamine. The reaction of N,N-diethylhydroxylamine with tert-butylhydroperoxide has been studied. It participates in the preparation of symmetrical and an isomeric mixture of unsymmetrical phthalocyanines. It undergoes degradation on exposure to radiation and affords light hydrocarbons. Qualitative and quantitative analyses of the produced hydrocarbons have been reported. It also participates in the conversion of quinones and quinonemonosulfonimide to the corresponding hydroquinones and sulfonylaminophenols, respectively.
signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
113.0 °F - closed cup
flash_point_c
45 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Qualitative and quantitative analysis of the light hydrocarbons produced by radiation degradation of N, N-diethylhydroxylamine.
Wang J, et al.
J. Radioanal. Nucl. Chem., 262(2), 451-453 (2004)
Reduction of quinones and quinonemonosulfonimides with N, N-diethylhydroxylamine.
Fujita S and Sano K.
The Journal of Organic Chemistry, 44(15), 2647-2651 (1979)
Oxidation of N, N-dialkyl hydroxylamines with t-butyl hydroperoxide. A new synthesis for nitrones.
Mare HDL and Coppinger GM.
The Journal of Organic Chemistry, 28(4), 1068-1070 (1963)
Novel and Mild Route to Phthalocyanines and 3-Iminoisoindolin-1-ones via N, N-Diethylhydroxylamine-Promoted Conversion of Phthalonitriles and a Dramatic Solvent-Dependence of the Reaction.
Luzyanin KV, et al.
Advanced Synthesis & Catalysis, 350(1), 135-142 (2008)
Gino A DiLabio et al.
Physical chemistry chemical physics : PCCP, 9(13), 1629-1634 (2007-04-13)
Incorporating diversity into structures constructed from the organic modification of silicon surfaces requires the use of molecules that contain multiple substituents of different types. In this work we examine the possible dissociation pathways of diethylhydroxylamine (DEHA, (C(2)H(5))(2)NOH) on the surface
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