474606
(S,S)-(+)-N,N′-双(3,5-二-叔丁基亚水杨基)-1,2-环己二胺钴(II)
别名:
(S,S)-Co(salen), (S,S)-Jacobsen HKR catalyst
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关于此项目
线性分子式:
[[[(CH3)3C]2C6H2-2-(O-)CH=N]2C6H10]Co
化学文摘社编号:
分子量:
603.74
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352001
MDL number:
mp
>350 °C (lit.)
Quality Level
SMILES string
CC(C)(C)c1cc2C=[N@@H]3[C@H]4CCCC[C@@H]4[N@H]5=Cc6cc(cc(c6O[Co]35Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI
1S/C36H54N2O2.Co/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;/h17-22,29-30,39-40H,13-16H2,1-12H3;/q;+2/p-2/b37-21+,38-22+;/t29-,30-;/m0./s1
InChI key
ZFWPDJKMASHRPT-IKKUFEJKSA-L
Application
(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) may be used as a catalyst for the Jacobsen′s hydrolytic kinetic resolution of racemic epoxides, which is a key step during the multi-step synthesis of (+)-patulolide C, macrosphelides(I and G), (-)-(3S,6R)-3,6-dihydroxy-10-methylundecanoic acid, dodoneine, epidodoneine and protein kinase C epsilon (PKCe) inhibitors.
用于末端环氧化物的水解动力学拆分和内消旋环氧化物不对称开环的催化剂。
Legal Information
经 Shasun Chemicals and Drugs Limited 授权销售。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
A Concise Synthesis of (-)-(3S, 6R)-3, 6-Dihydroxy-10-methylundecanoic Acid Using a Cross-Metathesis Approach.
Sabitha G, et al.
Synthesis, 2010(07), 1217-1222 (2010)
RCM mediated synthesis of macrosphelides I and G.
Sharma GVM, and Babu KV.
Tetrahedron Asymmetry, 18(18), 2175-2184 (2007)
Jacobsen, E.N. et al.
Tetrahedron Letters, 38, 773-773 (1997)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 474606-5G | 04061832623276 |
| 474606-25G | 04061832623269 |
| 474606-1G | 04061826083819 |