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Merck
CN

477567

Sigma-Aldrich

5,10,15,20-四(4-羟基苯基)-21H,23H-卟吩

Dye content 95 %

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关于此项目

经验公式(希尔记法):
C44H30N4O4
化学文摘社编号:
分子量:
678.73
MDL编号:
UNSPSC代码:
12171500
PubChem化学物质编号:
NACRES:
NA.47
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表单

powder

质量水平

组成

Dye content, 95%

mp

>300 °C (lit.)

λmax

421 nm

ε (消光系数)

≥285000 at 417-423 nm in methanol at 0.001 g/L

应用

diagnostic assay manufacturing
hematology
histology

储存温度

room temp

SMILES字符串

Oc1ccc(cc1)-c2c3ccc(n3)c(-c4ccc(O)cc4)c5ccc([nH]5)c(-c6ccc(O)cc6)c7ccc(n7)c(-c8ccc(O)cc8)c9ccc2[nH]9

InChI

1S/C44H30N4O4/c49-29-9-1-25(2-10-29)41-33-17-19-35(45-33)42(26-3-11-30(50)12-4-26)37-21-23-39(47-37)44(28-7-15-32(52)16-8-28)40-24-22-38(48-40)43(36-20-18-34(41)46-36)27-5-13-31(51)14-6-27/h1-24,45,48-52H/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-

InChI key

VFHDWGAEEDVVPD-LWQDQPMZSA-N

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一般描述

5,10,15,20-四(4-羟基苯基)-21H,23H-卟吩(TPPOH, 2H-OHTPP)是一种非手性卟啉衍生物。

应用

它可被用于制备基于卟啉的基质用于通过基质辅助激光解吸/电离(MALDI)质谱进行水溶性维生素的检测。它还可被用于制备5,10,15,20-四(4-聚乙烯氧基)苯基)卟啉。插入了2H-OHTPP的纳米多孔二氧化硅赋予了其气体敏感性,可用于通过表面等离子体共振检测NO2

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

危险分类

Eye Dam. 1 - Skin Corr. 1A - STOT SE 3

靶器官

Respiratory system

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Xiwen Li et al.
The journal of physical chemistry. B, 111(17), 4342-4348 (2007-04-06)
J-aggregates of the diacid form of tetra(p-hydroxyphenyl)porphyrin (THPP) were found to be stable in nonionic micellar solution in the presence of trace ionic surfactant with an oxyacid headgroup. The excitation energy of exciton coupling depends systematically on the headgroups of
Enhancing the gas sensitivity of surface plasmon resonance with a nanoporous silica matrix.
Berrier A, et al.
Sens. Actuators, 160(1), 181-188 (2011)
Yvette Niamien Konan et al.
European journal of pharmaceutics and biopharmaceutics : official journal of Arbeitsgemeinschaft fur Pharmazeutische Verfahrenstechnik e.V, 55(1), 115-124 (2003-01-29)
A photosensitizer, meso-tetra(4-hydroxyphenyl)porphyrin, was incorporated into sub-150 nm nanoparticles using the emulsification-diffusion technique in order to perform sterilization by filtration using 0.22 microm membranes. The three selected polyesters (poly(D,L-lactide-co-glycolide), (50:50 PLGA, 75:25 PLGA) and poly(D,L-lactide (PLA)) for the nanoparticle production
Yanli Quan et al.
The Analyst, 137(4), 944-952 (2011-12-21)
A novel idea on the basis of 5,10,15,20-tetrakis(4-hydroxyphenyl)porphyrin (THPP) functionalized carbon nanotubes (CNTs) film was developed to simulate the chromatographic separation, which was able to rapidly and simultaneously detect dihydroxybenzene isomers based on their different oxidation potentials and corresponding currents.
M C Berenbaum et al.
British journal of cancer, 54(5), 717-725 (1986-11-01)
We compared para-, meta- and ortho-isomers of meso-tetra(hydroxyphenyl)porphyrin (p-, m- and o-THPP) and the potassium salt of the para compound (K-p-THPP) with haematoporphyrin derivative (HpD) and Photofrin II in their ability to sensitise tumours, skin and brain to light. HpD

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