477966
烯丙基联苯氧化膦
97%
别名:
Diphenyl-2-propenylphosphine oxide, NSC 616249, NSC 98715
方案
97%
反应适用性
reagent type: ligand
mp
110-114 °C (lit.)
官能团
phosphine
SMILES字符串
C=CCP(=O)(c1ccccc1)c2ccccc2
InChI
1S/C15H15OP/c1-2-13-17(16,14-9-5-3-6-10-14)15-11-7-4-8-12-15/h2-12H,1,13H2
InChI key
PGPAPANRSWMTQO-UHFFFAOYSA-N
应用
Reactant for:
- Preparaton of a-substituted alkylsilanes via regio- and chemoselective copper-catalyzed silylzincation and electrophilic substitution from terminal alkenes, and prepn. of α-substituted alcohols via Fleming-Tamao oxidation of alkylsilanes
- Olefin isomerization with Grubbs′ catalysts occluded in a hydrophobic matrix of polydimethylsiloxane (PDMS)
- C9-substituted trans-hydrindene via diastereotopic group-selective intramolecular Diels-Alder reaction
- Isomerization of allyl group-containing compounds to propenyl group-containing compounds in the presence of a Grubbs second-generation Ru catalyst
- Ruthenium-catalyzed olefin cross-metathesis of vinyl and allyl phosphine oxides to give alkenyl phosphine oxides and bis-phosphine oxides
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
储存分类代码
13 - Non Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
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