481408
二环己基氯化膦
97%
别名:
二环己基次膦酰氯, 二环己基氯化膦, 二环己基氯膦
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关于此项目
线性分子式:
(C6H11)2PCl
化学文摘社编号:
分子量:
232.73
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
MDL number:
Quality Level
assay
97%
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
refractive index
n20/D 1.533 (lit.)
bp
165 °C/12 mmHg (lit.)
density
1.054 g/mL at 25 °C (lit.)
functional group
phosphine
SMILES string
ClP(C1CCCCC1)C2CCCCC2
InChI
1S/C12H22ClP/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h11-12H,1-10H2
InChI key
AKJFBIZAEPTXIL-UHFFFAOYSA-N
Application
二环己基氯化膦可用作反应物参与合成：
它还可用作原料制备其他配体，如二环己基氧化膦、膦基取代的N-芳基吡咯 、二叔丁基（（二环己基膦基）甲基）膦 、二环己基环戊基膦。这些配体可用于钯催化的交叉偶联反应。
- 1,2-双（二环己基次膦氧基）乙烷配体（在存在三乙胺的情况下与乙二醇通过Michaelis−-Arbuzov重排反应）。
- 1,1,2,2-四环己基二膦一硫化物配体（通过LiS处理）。
它还可用作原料制备其他配体，如二环己基氧化膦、膦基取代的N-芳基吡咯 、二叔丁基（（二环己基膦基）甲基）膦 、二环己基环戊基膦。这些配体可用于钯催化的交叉偶联反应。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
相关内容
Phosphine Ligand Application Guide
A sulfur mimic of 1, 1-bis (diphenylphosphino) methane: a new ligand opens up
Sues PE, et al.
Chemical Communications (Cambridge, England), 50(36), 4707-4710 (2014)
Practical synthesis of new and highly efficient ligands for the Suzuki reaction of aryl chlorides
Zapf A, et al.
Chemical Communications (Cambridge, England), 19(1), 38-39 (2004)
Sterically crowded diphosphinomethane ligands: molecular structures, UV-photoelectron spectroscopy and a convenient general synthesis of t Bu 2 PCH 2 P t Bu 2 and related species
Eisentrager, F, et al.
New. J. Chem., 27(3), 540-550 (2003)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 481408-5G | 04061832388618 |
| 481408-1G | 04061838120069 |