483761
N-Boc-L-脯氨醛
97%
别名:
(S)-N-Boc-吡咯烷-2-甲醛, N-(叔丁氧羰基)-L-脯氨醛
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关于此项目
经验公式（希尔记法）:
C10H17NO3
化学文摘社编号:
分子量:
199.25
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352209
MDL number:
InChI
1S/C10H17NO3/c1-10(2,3)14-9(13)11-6-4-5-8(11)7-12/h7-8H,4-6H2,1-3H3/t8-/m0/s1
SMILES string
[H]C(=O)[C@@H]1CCCN1C(=O)OC(C)(C)C
InChI key
YDBPZCVWPFMBDH-QMMMGPOBSA-N
assay
97%
optical activity
[α]20/D −101°, c = 0.66 in chloroform
reaction suitability
reaction type: Boc solid-phase peptide synthesis
refractive index
n20/D 1.462 (lit.)
bp
211 °C (lit.)
density
1.063 g/mL at 25 °C (lit.)
application(s)
peptide synthesis
storage temp.
−20°C
Application
用于降一叶萩碱型生物碱和依靛蓝双酮碳骨架的重要结构单元。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
135.0 °F - closed cup
flash_point_c
57.2 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Tetrahedron Letters, 45, 2985-2985 (2004)
Ramon Alibés et al.
Organic letters, 6(11), 1813-1816 (2004-05-21)
The syntheses of securinine and (-)-allonorsecurinine have been achieved starting from easily available alpha-amino acid derivatives and using as key steps a RCM and a Heck reaction for the formation of rings D and C, respectively. [reaction: see text]
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