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489174

苄氧基丙酮

Name: 苄氧基丙酮
Brand: ALDRICH

90%

别名:

1-苄氧基-2-丙酮

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关于此项目

线性分子式:

C₆H₅CH₂OCH₂COCH₃

化学文摘社编号:

22539-93-1

分子量:

164.20

NACRES:

NA.22

PubChem Substance ID:

24872460

UNSPSC Code:

12352100

MDL number:

MFCD01863536

Assay:

90%

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属性

Quality Segment

200

assay

90%

impurities

3% (benzyloxy)acetic acid, 3% benzyl alcohol

refractive index

n20/D 1.512 (lit.)

bp

259 °C (lit.)

density

1.04 g/mL at 25 °C (lit.)

functional group

ether, ketone, phenyl

SMILES string

CC(=O)COCc1ccccc1

InChI

1S/C10H12O2/c1-9(11)7-12-8-10-5-3-2-4-6-10/h2-6H,7-8H2,1H3

InChI key

YHMRKVGUSQWDGZ-UHFFFAOYSA-N

说明

General description

Benzyloxyacetone (α-Benzyloxyacetone) is an α-substituted acetone. It undergoes direct aldol reaction with 4-nitrobenzaldehyde in the presence of (S)-BINAM-L-prolinamide/benzoic acid to form predominantly the syn-diasteroisomer.

Application

Benzyloxyacetone (1-Benzyloxy-2-propanone) may be used in the synthesis of:

7-benzyloxy-6-methyl-5-hepten-1-yne
(Z)-2-methylhept-2-en-6-yn-1-o1
(S)-(+)-1,2-propanediol, 1-benzyl ether

It may be used as a starting material in synthesizing (2S,4RS)-4-acetoxy-2-[(benzyloxy)methyl]-2-methyldioxolane and (2R,4RS)-4-acetoxy-2-[(benzyloxy)methyl]-2-methyldioxolane.

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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