494119
双(2-甲氧基)乙基三氟化硫
别名:
双(2-甲氧基乙基)氨基三氟化硫
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关于此项目
线性分子式:
(CH3OCH2CH2)2NSF3
化学文摘社编号:
分子量:
221.24
UNSPSC Code:
12352101
PubChem Substance ID:
MDL number:
InChI
1S/C6H14F3NO2S/c1-11-5-3-10(4-6-12-2)13(7,8)9/h3-6H2,1-2H3
SMILES string
COCCN(CCOC)S(F)(F)F
InChI key
APOYTRAZFJURPB-UHFFFAOYSA-N
density
1.2 g/mL at 25 °C (lit.)
storage temp.
2-8°C
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Legal Information
Other Notes
有关 Deoxo-Fluor 和 DAST 与有机化合物亲核氟化反应近期工作的综述，请参阅 Synthesis, 2002, 17, 2561。
通过酰基氟的中间性，羧酸一瓶转化为酰胺。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1A - Water-react 2
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
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Jonathan M White et al.
The Journal of organic chemistry, 69(7), 2573-2576 (2004-03-31)
The use of the Deoxo-Fluor reagent is a versatile method for acyl fluoride generation and subsequent one-flask amide coupling. It provides mild conditions and facile purification of the desired products in good to excellent yields. We have explored the utility
Synthesis, 2561-2561 (2002)
商品
This technical article discusses Bis(2-methoxyethyl)aminosulfur Trifluoride (Deoxo-Fluor®).
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