494585
二异丙基氨基锂 溶液
1.8 M in THF/heptane/ethylbenzene
别名:
LDA
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关于此项目
线性分子式:
[(CH3)2CH]2NLi
化学文摘社编号:
分子量:
107.12
Beilstein:
3655042
MDL编号:
UNSPSC代码:
12352001
PubChem化学物质编号:
浓度
1.8 M in THF/heptane/ethylbenzene
沸点
65 °C
密度
0.836 g/mL at 25 °C
储存温度
2-8°C
SMILES字符串
[Li]N(C(C)C)C(C)C
InChI
1S/C6H14N.Li/c1-5(2)7-6(3)4;/h5-6H,1-4H3;/q-1;+1
InChI key
ZCSHNCUQKCANBX-UHFFFAOYSA-N
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应用
由酮与 Ti(OiPr)4 和 LDA 作用制备的烯醇钛,发生有效自由基三氟甲基化反应,从而以高产率提供三氟甲基酮。还用于芳基磺酰噁唑烷酮的直接邻锂化反应以制备 N-取代糖精类似物。
警示用语:
Danger
危险分类
Aquatic Chronic 2 - Asp. Tox. 1 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3
靶器官
Central nervous system, hearing organs, Respiratory system
补充剂危害
储存分类代码
3 - Flammable liquids
WGK
WGK 2
闪点(°F)
10.4 °F - closed cup
闪点(°C)
-12 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles
法规信息
新产品
此项目有
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