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Merck
CN

494585

Sigma-Aldrich

二异丙基氨基锂 溶液

1.8 M in THF/heptane/ethylbenzene

别名:

LDA

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关于此项目

线性分子式:
[(CH3)2CH]2NLi
化学文摘社编号:
分子量:
107.12
Beilstein:
3655042
MDL编号:
UNSPSC代码:
12352001
PubChem化学物质编号:
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浓度

1.8 M in THF/heptane/ethylbenzene

沸点

65 °C

密度

0.836 g/mL at 25 °C

储存温度

2-8°C

SMILES字符串

[Li]N(C(C)C)C(C)C

InChI

1S/C6H14N.Li/c1-5(2)7-6(3)4;/h5-6H,1-4H3;/q-1;+1

InChI key

ZCSHNCUQKCANBX-UHFFFAOYSA-N

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应用

由酮与 Ti(OiPr)4 和 LDA 作用制备的烯醇钛,发生有效自由基三氟甲基化反应,从而以高产率提供三氟甲基酮。还用于芳基磺酰噁唑烷酮的直接邻锂化反应以制备 N-取代糖精类似物。

警示用语:

Danger

危险分类

Aquatic Chronic 2 - Asp. Tox. 1 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3

靶器官

Central nervous system, hearing organs, Respiratory system

补充剂危害

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(°F)

10.4 °F - closed cup

闪点(°C)

-12 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Tetrahedron Letters, 47, 6405-6405 (2006)
Journal of Fluorine Chemistry, 127, 539-539 (2006)
Joshua D Schaefferkoetter et al.
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In the context of investigating the potential of low-dose PET imaging for screening applications, we developed methods to assess small lesion detectability as a function of the number of counts in the scan. We present here our methods and preliminary
Juan Eugenio Iglesias et al.
NeuroImage, 115, 117-137 (2015-05-06)
Automated analysis of MRI data of the subregions of the hippocampus requires computational atlases built at a higher resolution than those that are typically used in current neuroimaging studies. Here we describe the construction of a statistical atlas of the
Giovanna Lopane et al.
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In current clinical practice, assessment of levodopa-induced dyskinesias (LIDs) in Parkinson's disease (PD) is based on semiquantitative scales or patients' diaries. We aimed to assess the feasibility, clinical validity, and usability of a waist-worn inertial sensor for discriminating between LIDs

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