InChI key
YBNBOGKRCOCJHH-UHFFFAOYSA-N
InChI
1S/C10H18O2Si2/c1-13(2,11)9-5-7-10(8-6-9)14(3,4)12/h5-8,11-12H,1-4H3
SMILES string
C[Si](C)(O)c1ccc(cc1)[Si](C)(C)O
assay
95%
mp
133-136 °C (lit.)
Application
钯催化交叉偶联反应的有效硅亲核试剂。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Scott E Denmark et al.
Journal of the American Chemical Society, 130(48), 16382-16393 (2008-11-13)
The sodium salts of allyldimethylsilanol and 2-butenyldimethylsilanol undergo palladium-catalyzed cross-coupling with a wide variety of aryl bromides to afford allylated and crotylated arenes. The coupling of both silanolates required extensive optimization to deliver the expected products in high yields. The
Denmark, S. E.; Ober, M. H.
Aldrichimica Acta, 36, 75-75 (2003)
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