497940
3-氰苯基碘化锌 溶液
0.5 M in THF
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关于此项目
线性分子式:
NCC6H4ZnI
化学文摘社编号:
分子量:
294.41
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
concentration
0.5 M in THF
density
0.998 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
I[Zn]c1cccc(c1)C#N
InChI
1S/C7H4N.HI.Zn/c8-6-7-4-2-1-3-5-7;;/h1-2,4-5H;1H;/q;;+1/p-1
InChI key
MWVOJRQBIBGPBW-UHFFFAOYSA-M
Application
3-Cyanophenylzinc iodide can be used:
- As a reagent/substrate in the palladium-catalyzed synthesis of 5-substituted 2-furaldehydes of biological importance.
- As a substrate in the di-functionalization of indenes via α-carbonylalkylarylation to yield α-carbonyl- alkylarylated indenes.
Legal Information
Rieke® Metals, Inc. 产品 ®Rieke Metals, Inc. 的注册商标
Rieke is a registered trademark of Rieke Metals, Inc.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
1.0 °F - closed cup
flash_point_c
-17.22 °C - closed cup
法规信息
新产品
此项目有
Nickel-Catalyzed α-Carbonylalkylarylation of Vinylarenes: Expedient Access to γ, γ-Diarylcarbonyl and Aryltetralone Derivatives
Shekhar KC, et al.
Angewandte Chemie (International ed. in English), 132(21), 8124-8128 (2020)
A convenient synthesis of 5-aryl-and 5-heteroaryl-2-furaldehydes by the cross-coupling reaction of organozincs
Kim S and Rieke RD
Tetrahedron Letters, 51(19), 2657-2659 (2010)
Seung-Hoi Kim et al.
The Journal of organic chemistry, 78(5), 1984-1993 (2012-10-19)
Facile synthetic routes for the preparation of a wide range of 5-substituted 2-furaldehydes have been revealed. They were accomplished through either Pd-catalyzed cross-coupling reaction of various aryl- and heteroarylzinc halides with 5-bromo-2-furaldehyde or utilization of a new organozinc reagent, 5-(1,3-dioxolan-2-yl)-2-furanylzinc
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 497940-50ML | 04061837704796 |