498041
环戊基溴化锌 溶液
0.5 M in THF
别名:
Bromo(cyclopentyl)zinc, Bromocyclopentylzinc
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关于此项目
线性分子式:
C5H9ZnBr
化学文摘社编号:
分子量:
214.42
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
产品名称
环戊基溴化锌 溶液, 0.5 M in THF
InChI
1S/C5H9.BrH.Zn/c1-2-4-5-3-1;;/h1H,2-5H2;1H;/q;;+1/p-1
SMILES string
Br[Zn]C1CCCC1
InChI key
GOPYCBPMCCJYSN-UHFFFAOYSA-M
concentration
0.5 M in THF
density
0.955 g/mL at 25 °C
storage temp.
2-8°C
Quality Level
Legal Information
Rieke® Metals, Inc. 制造。®Rieke Metals, Inc. 的注册商标。
Application
Cyclopentylzinc bromide is an organozinc reagent that can be used in:
- The synthesis of polyfunctional indoles by reacting with various aryldiazonium salts via Fischer indole synthesis.
- Negishi cross-coupling reactions with various haloarenes in presence of Pd-complex catalyst.
- The preparation of aryl alkyl ketones by alkylation of aryl N-methyl-N-tosyl or N-benzyl-N-(tert-butoxycarbonyl) amide derivatives in the presence of Ni catalyst and imidazolidinylidene ligand.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3 - Water-react 2
target_organs
Respiratory system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
法规信息
危险化学品
此项目有
Efficient preparation of polyfunctional indoles via a zinc organometallic variation of the Fischer indole synthesis
Zhang Z-G, et al.
Synthesis, 2011(01), 23-29 (2011)
Nickel-catalyzed alkylation of amide derivatives
Simmons BJ, et al.
ACS Catalysis, 6(5), 3176-3179 (2016)
Mild Negishi cross-coupling reactions catalyzed by acenaphthoimidazolylidene palladium complexes at low catalyst loadings
Liu Z, et al.
The Journal of Organic Chemistry, 78(15), 7436-7444 (2013)
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