498815
(S)-(−)-3-甲氧基-2-甲基-3-氧代丙基溴化锌 溶液
0.5 M in THF
登录 查看组织和合同定价。
选择尺寸
关于此项目
线性分子式:
CH3O2CCH(CH3)CH2ZnBr
化学文摘社编号:
分子量:
246.42
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C5H9O2.BrH.Zn/c1-4(2)5(6)7-3;;/h4H,1H2,2-3H3;1H;/q;;+1/p-1/t4-;;/m0../s1
SMILES string
COC(=O)[C@H](C)C[Zn]Br
InChI key
ZYPPBSJLXDMOPY-FHNDMYTFSA-M
concentration
0.5 M in THF
density
0.965 g/mL at 25 °C
storage temp.
2-8°C
Application
(S)-(−)-3-Methoxy-2-methyl-3-oxopropylzinc bromide can be used:
- As an intermediate in the total synthesis of macrolide derivative laingolide B stereoisomers.
- As a substrate in the synthesis of (3R)-1-benzyl-3-methylpyrrolidine-2,5-dione (aliphatic carboxamide) using NiII-pincer complexes.
Legal Information
Rieke® Metals, Inc. 产品 ®Rieke Metals, Inc. 的注册商标
signalword
Danger
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3 - Water-react. 2
法规信息
新产品
此项目有
Synthesis of Aliphatic Carboxamides Mediated by Nickel NN2-Pincer Complexes and Adaptation to Carbon-Isotope Labeling
Neumann KT, et al.
Chemistry?A European Journal , 24(56), 14946-14949 (2018)
Total Synthesis of Laingolide B Stereoisomers and Assignment of Absolute Configuration
Cui C and Dai W
Organic Letters, 20(11), 3358-3361 (2018)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持