51432
(S)-(-)-α-乙基苄胺
≥95.0% (GC)
别名:
(S)-(-)-1-苯丙胺
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关于此项目
经验公式（希尔记法）:
C9H13N
化学文摘社编号:
分子量:
135.21
Beilstein:
2412016
MDL编号:
UNSPSC代码:
12352116
PubChem化学物质编号:
NACRES:
NA.22
方案
≥95.0% (GC)
旋光性
[α]20/D −20±2°, neat
光学纯度
enantiomeric ratio: ≥99.0:1.0 (GC)
折射率
n20/D 1.520
密度
0.940 g/mL at 20 °C (lit.)
SMILES字符串
CC[C@H](N)c1ccccc1
InChI
1S/C9H13N/c1-2-9(10)8-6-4-3-5-7-8/h3-7,9H,2,10H2,1H3/t9-/m0/s1
InChI key
AQFLVLHRZFLDDV-VIFPVBQESA-N
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应用
(S)-(−)-α-Ethylbenzylamine can be used:
- To prepare optically active copolyacrylate polymers with sensing and chiroptical properties.
- As a chiral auxiliary in the preparation of enantioenriched indanone derived α-SCF2H β-keto esters.
警示用语：
Danger
危险声明
危险分类
Acute Tox. 4 Oral - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
170.6 °F
闪点(°C)
77 °C
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Synthesis and characterization of new optically active poly (acrylamide/methacrylurea-co-vinyl acetate) copolymers with dansyl units
Murariu M and Buruiana EC
Designed Monomers and Polymers, 18(2), 118-128 (2015)
Asymmetric Electrophilic Difluoromethylthiolation of Indanone-Based β-Keto Esters Using Difluoromethanesulfonyl Hypervalent Iodonium Ylides
Gondo S, et al.
Molecules (Basel), 24(2), 221-221 (2019)
商品
Chiral amines have found widespread application in asymmetric synthesis serving, for instance, as chiral bases in enantioselective deprotonation reactions or being valuable substances for resolving racemic mixtures of acids.
手性胺已广泛用于不对称合成，例如用作对映选择性去质子化反应中的手性碱，或用于拆分消旋的酸。
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