51432
(S)-(-)-α-乙基苄胺
≥95.0% (GC)
别名:
(S)-(-)-1-苯丙胺
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关于此项目
经验公式（希尔记法）:
C9H13N
化学文摘社编号:
分子量:
135.21
UNSPSC Code:
12352116
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2412016
Assay:
≥95.0% (GC)
InChI
1S/C9H13N/c1-2-9(10)8-6-4-3-5-7-8/h3-7,9H,2,10H2,1H3/t9-/m0/s1
SMILES string
CC[C@H](N)c1ccccc1
InChI key
AQFLVLHRZFLDDV-VIFPVBQESA-N
assay
≥95.0% (GC)
optical activity
[α]20/D −20±2°, neat
optical purity
enantiomeric ratio: ≥99.0:1.0 (GC)
refractive index
n20/D 1.520
density
0.940 g/mL at 20 °C (lit.)
Application
(S)-(−)-α-Ethylbenzylamine can be used:
- To prepare optically active copolyacrylate polymers with sensing and chiroptical properties.
- As a chiral auxiliary in the preparation of enantioenriched indanone derived α-SCF2H β-keto esters.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
170.6 °F
flash_point_c
77 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Synthesis and characterization of new optically active poly (acrylamide/methacrylurea-co-vinyl acetate) copolymers with dansyl units
Murariu M and Buruiana EC
Designed Monomers and Polymers, 18(2), 118-128 (2015)
Asymmetric Electrophilic Difluoromethylthiolation of Indanone-Based β-Keto Esters Using Difluoromethanesulfonyl Hypervalent Iodonium Ylides
Gondo S, et al.
Molecules (Basel), 24(2), 221-221 (2019)
商品
Chiral amines have found widespread application in asymmetric synthesis serving, for instance, as chiral bases in enantioselective deprotonation reactions or being valuable substances for resolving racemic mixtures of acids.
手性胺已广泛用于不对称合成，例如用作对映选择性去质子化反应中的手性碱，或用于拆分消旋的酸。
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