526169
1,8-二甲基-1,4,8,11-四氮杂环十四烷
别名:
1,8-Dimethylcyclam
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关于此项目
经验公式（希尔记法）:
C12H28N4
化学文摘社编号:
分子量:
228.38
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
InChI
1S/C12H28N4/c1-15-9-3-5-14-8-12-16(2)10-4-6-13-7-11-15/h13-14H,3-12H2,1-2H3
SMILES string
CN1CCCNCCN(C)CCCNCC1
InChI key
BNLDMZVBFXARKJ-UHFFFAOYSA-N
refractive index
n20/D 1.4940 (lit.)
bp
98-99 °C (lit.)
density
0.944 g/mL at 25 °C (lit.)
Quality Level
Application
1,8-Dimethyl-1,4,8,11-tetraazacyclotetradecane may be used as a precursor for the synthesis of `trans′-difunctionalized derivatives. It may also be used in the synthesis of 4,11-bis(N-pyren-1-yl-acetamide)-1,8-dimethyl-1,4,8,11-tetraazacyclotetradecane.
Reactant for:
- Ferromagnetic coupling of copper(II) and nickel(II) complexes
- Preparation of cyclam bridged dinuclear platinum(II) complex as an antitumor agent
- Preparation of dimethylcyclam based fluoroionophore having Hg2+- and Cd2+-selective signaling behaviors
General description
1,8-Dimethyl-1,4,8,11-tetraazacyclotetradecane is a heterocyclic building block.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
195.1 °F - closed cup
flash_point_c
90.6 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Copper (II) and Nickel (II) Complexes oftrans'-Difunctionalized Tetraaza Macrocycles.
Comparone A and Kaden TA.
Helvetica Chimica Acta, 81(10), 1765-1772 (1998)
So-Youn Moon et al.
The Journal of organic chemistry, 70(6), 2394-2397 (2005-03-12)
[reaction: see text] A new fluoroionophore has been synthesized by appending two signaling pyrenylacetamide subunits on the binding motif of 1,8-dimethylcyclam. The designed compound exhibited highly selective and sensitive fluoroionophoric behavior toward Hg(2+) ions of excimer emission in aqueous dioxane
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