528382
2-甲氧基-1-萘甲酸
98%
别名:
2-甲氧基萘甲酸
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关于此项目
线性分子式:
CH3OC10H6CO2H
化学文摘社编号:
分子量:
202.21
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
213-429-5
MDL number:
Assay:
98%
InChI key
OSTYZAHQVPMQHI-UHFFFAOYSA-N
InChI
1S/C12H10O3/c1-15-10-7-6-8-4-2-3-5-9(8)11(10)12(13)14/h2-7H,1H3,(H,13,14)
SMILES string
COc1ccc2ccccc2c1C(O)=O
assay
98%
mp
177-180 °C (lit.)
functional group
carboxylic acid
General description
2-Methoxy-1-naphthoic acid is the 3-methoxy derivative of 1-napthoic acid. It can be prepared from a Grignard reagent derived from 1-bromo-2-methoxynaphthalene. 2-Methoxy-1-naphthoic acid undergoes Birch reduction to afford 2-methoxy-1,4,5,8-tetrahydro-1-naphthoic acid.
Application
2-Methoxy-1-naphthoic acid may be used in the synthesis of chiral (methoxynaphthyl)oxazoline.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Enantioselective synthesis of binaphthyls via nucleophilic aromatic substitution on chiral oxazolines.
Meyers AI and Lutomski KA.
Journal of the American Chemical Society, 104(3), 879-881 (1982)
The Reaction of Phenyl 2-Methoxy-1-naphthoate with Grignard Reagents. A New Route to Fluorenones.
Fuson RC and Wassmundt FW.
Journal of the American Chemical Society, 78(20), 5409-5413 (1956)
Birch Reduction of 2-Naphthoic and of ortho-Methoxynaphthoic Acids.
Eliel EL and Hoover TE.
The Journal of Organic Chemistry, 24(7), 938-942 (1959)
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