528595
2,6-二乙氧基苯甲酸
97%
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关于此项目
线性分子式:
(C2H5O)2C6H3CO2H
化学文摘社编号:
分子量:
210.23
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
方案
97%
表单
solid
mp
131-135 °C (lit.)
SMILES字符串
CCOc1cccc(OCC)c1C(O)=O
InChI
1S/C11H14O4/c1-3-14-8-6-5-7-9(15-4-2)10(8)11(12)13/h5-7H,3-4H2,1-2H3,(H,12,13)
InChI key
XUIVSLVJEQVKLB-UHFFFAOYSA-N
一般描述
2,6-Diethoxybenzoic acid undergoes catalytic hydrodecarboxylation in the presence of toluene/D2O to afford 2-d-1,3-diethoxybenzene.
储存分类代码
13 - Non Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Jing Zhang et al.
Journal of the American Chemical Society, 135(46), 17270-17273 (2013-11-01)
Through-space metal/hydrogen shift is an important strategy for transition-metal-catalyzed C-H bond activation. Here we describe the synthesis and characterization of a Rh(I) 2,6-dimethoxybenzoate complex that underwent stoichiometric rearrangement via a highly unusual 1,3-rhodium migration. This aryl-to-aryl 1,3-Rh/H shift was also
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