539341
2,3-二氯苄胺
97%
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关于此项目
线性分子式:
Cl2C6H3CH2NH2
化学文摘社编号:
分子量:
176.04
UNSPSC Code:
12352100
PubChem Substance ID:
EC Number:
202-382-6
MDL number:
Assay:
97%
InChI key
JHBVZGONNIVXFJ-UHFFFAOYSA-N
InChI
1S/C7H7Cl2N/c8-6-3-1-2-5(4-10)7(6)9/h1-3H,4,10H2
SMILES string
NCc1cccc(Cl)c1Cl
assay
97%
refractive index
n20/D 1.583 (lit.)
bp
136-140 °C/18 mmHg (lit.)
density
1.321 g/mL at 25 °C (lit.)
General description
2,3-Dichlorobenzylamine is a halogenated benzylamine derivative. It undergoes oxidation with hydrogen peroxide in the presence of V2O5 to afford N-(2,3-dichlorobenzyl) 2,3-dichlorobenzaldimine.
Application
2,3-Dichlorobenzylamine may be used in the synthesis of 5-(2′,3′-dichlorobenzylamino)uracil and 8-substituted quinolines.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
221.0 °F - closed cup
flash_point_c
105 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Novel 5-(N-Alkylaminouracil) Acyclic Nucleosides.
Boncel S, et al.
Synthesis, 2011(04), 603-610 (2011)
J David Becherer et al.
Journal of medicinal chemistry, 58(17), 7021-7056 (2015-08-13)
Starting from the micromolar 8-quinoline carboxamide high-throughput screening hit 1a, a systematic exploration of the structure-activity relationships (SAR) of the 4-, 6-, and 8-substituents of the quinoline ring resulted in the identification of approximately 10-100-fold more potent human CD38 inhibitors.
Guobiao Chu et al.
Organic & biomolecular chemistry, 8(20), 4716-4719 (2010-08-18)
The current syntheses of imines from benzylamines are often performed in organic solvents or under harsh reaction conditions. Clean oxidation of primary benzylamines to imines has been successfully achieved using H(2)O(2) in water at room temperature catalyzed by V(2)O(5). Among
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