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经验公式(希尔记法):
C10H12O4S
化学文摘社编号:
分子量:
228.26
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3592142
Assay:
98%
InChI
1S/C10H12O4S/c1-8-2-4-10(5-3-8)15(11,12)14-7-9-6-13-9/h2-5,9H,6-7H2,1H3/t9-/m1/s1
SMILES string
Cc1ccc(cc1)S(=O)(=O)OC[C@H]2CO2
InChI key
NOQXXYIGRPAZJC-SECBINFHSA-N
assay
98%
mp
46-49 °C (lit.)
functional group
ether, tosylate
storage temp.
2-8°C
Quality Level
Application
(2R)-(-)-Glycidyl tosylate may be used to prepare:
- 1-O-hexadecyl-sn-glycerol 3-O-p-toluenesulfonate by reacting with 1-hexadecanol in the presence of boron trifluoride etherate.
- 4-Oxiranylmethoxy-(1H)-indole by reacting with 4-hydroxyindole in the presence of sodium hydride.
- [18F]Epifluorohydin, an intermediate for preparing of [18F]fluoromisonidazole.
Legal Information
经 Shasun Chemicals and Drugs Limited 授权,使用 Jacobsen HKR 技术制造。
signalword
Danger
hcodes
Hazard Classifications
Aquatic Chronic 2 - Carc. 1B - Eye Dam. 1 - Muta. 2 - Skin Sens. 1
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
>230.0 °F
flash_point_c
> 110 °C
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Facile diacylation of glycidyl tosylate. Chiral synthesis of symmetric-chain glycerophospholipids.
Ali S and Bittman R
The Journal of Organic Chemistry, 53(23), 5547-5549 (1988)
A Radiosynthesis of fluorine-18.
Grierson JR, et al.
Journal of Nuclear Medicine, 30, 343-350 (1989)
Isosteric phosphonate analogs of ET-16-OMe. Synthesis and biological evaluation of the enantiomers of 2'-(Trimethylammonio) ethyl 4-(hexadecyloxy)-3-methoxybutanephosphonate and 2'-(trimethylammonio) ethyl 4-(hexadecylthio)-3-methoxybutanephosphonate.
Bittman R, et al.
Journal of Medicinal Chemistry, 37(3), 425-430 (1994)
Novel aryloxy-8-azabicyclo [3.2. 1] oct-3-enes with 5-HT transporter and 5-HT 1A affinity.
Gilbert AM, et al.
Bioorganic & Medicinal Chemistry Letters, 14(21), 5281-5284 (2004)
Henry, N. et al.
Tetrahedron Letters, 45, 1465-1465 (2004)
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