540595
(S)-(-)-3,3′-二溴-5,5′,6,6′,7,7′,8,8′-八氢-1,1′-二-2,2′-萘酚
97%
方案
97%
旋光性
[α]20/D −53°, c = 1 in THF
mp
145.5-148.5 °C (lit.)
官能团
bromo
InChI
1S/C20H20Br2O2/c21-15-9-11-5-1-3-7-13(11)17(19(15)23)18-14-8-4-2-6-12(14)10-16(22)20(18)24/h9-10,23-24H,1-8H2
InChI key
WDRTXCNGVVLRSZ-UHFFFAOYSA-N
一般描述
(S)-3,3′-Dibromo-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-bi-2,2′-naphthalenediol can be used in the synthesis of chiral bidentate hybrid ligands for asymmetric hydrogenation and hydroformylation reactions.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
Supramolecular control of ligand coordination and implications in hydroformylation reactions
Bellini R, et al.
Angewandte Chemie (International ed. in English), 123(32), 7480-7483 (2011)
Supramolecular hybrid bidentate ligands in asymmetric hydrogenation
Bellini R and Reek JNH
European Journal of Inorganic Chemistry, 2012(29), 4684-4693 (2012)
Coordination studies on supramolecular chiral ligands and application in asymmetric hydroformylation
Bellini R and Reek JNH
Chemistry?A European Journal , 18(23), 7091-7099 (2012)
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