54060
氢化辛可宁
≥95.0% (sum of enantiomers, HPLC)
别名:
二氢金鸡纳宁
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关于此项目
经验公式（希尔记法）:
C19H24N2O
化学文摘社编号:
分子量:
296.41
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
EC Number:
207-621-8
Beilstein/REAXYS Number:
4296749
MDL number:
InChI key
WFJNHVWTKZUUTR-QAMTZSDWSA-N
InChI
1S/C19H24N2O/c1-2-13-12-21-10-8-14(13)11-18(21)19(22)16-7-9-20-17-6-4-3-5-15(16)17/h3-7,9,13-14,18-19,22H,2,8,10-12H2,1H3/t13-,14-,18+,19-/m0/s1
SMILES string
CC[C@H]1CN2CC[C@H]1C[C@@H]2[C@@H](O)c3ccnc4ccccc34
assay
≥95.0% (sum of enantiomers, HPLC), ≥97.0% (NT)
optical activity
[α]20/D +197±4°, c = 0.25% in ethanol
mp
269-272 °C (lit.)
functional group
hydroxyl
Quality Level
Application
Hydrocinchonine is an alkaloid that can be used as a chiral base in:
- The 1,3-dipolar cycloaddition reactions of alkenes and azomethine ylides using silver fluoride.
- The aza-Henry reaction for the synthesis of molecules with optically active quaternary centers.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
A chiral molecular recognition approach to the formation of optically active quaternary centres in aza-Henry reactions
Knudsen KR and Jorgensen KA
Organic & Biomolecular Chemistry, 3(8), 1362-1364 (2005)
A convenient procedure for the catalytic asymmetric 1, 3-dipolar cycloaddition of azomethine ylides and alkenes
Alemparte C, et al.
Organic Letters, 7(21), 4569-4572 (2005)
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