540706
三(乙酰腈)三羰基钨(0)
别名:
三(乙腈)钨(0)
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关于此项目
线性分子式:
W(NCCH3)3(CO)3
化学文摘社编号:
分子量:
391.03
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352300
EC Number:
240-833-9
MDL number:
InChI key
MHVAYSUFFMSBKA-UHFFFAOYSA-N
InChI
1S/3C2H3N.3CO.W/c3*1-2-3;3*1-2;/h3*1H3;;;;
SMILES string
[W].[C-]#[O+].[C-]#[O+].[C-]#[O+].CC#N.CC#N.CC#N
reaction suitability
core: tungsten, reagent type: catalyst
mp
>300 °C (lit.)
Application
Catalyst for allylic substitutions
Reactant for:
Reactant for:
- Mixed disilyl-substituted cyclopentadiene derivatives
- Synthesis of catalytically active ansa compounds with cycloalkyl moieties
- Stepwise assembly of mixed metal dinuclear carbonyl complexes
- Cycloaddition of M(CO)3-coordinated-cyanoazepine with alkynes
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 2 Oral
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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