541486
2,6-二甲基-4-庚醇
80%
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线性分子式:
CH3CH(CH3)CH2CH(OH)CH2CH(CH3)CH3
化学文摘社编号:
分子量:
144.25
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
203-619-6
MDL number:
Assay:
80%
InChI key
HXQPUEQDBSPXTE-UHFFFAOYSA-N
InChI
1S/C9H20O/c1-7(2)5-9(10)6-8(3)4/h7-10H,5-6H2,1-4H3
SMILES string
CC(C)CC(O)CC(C)C
assay
80%
refractive index
n20/D 1.423 (lit.)
bp
178 °C (lit.)
density
0.809 g/mL at 25 °C (lit.)
functional group
hydroxyl
Quality Level
Application
2,6-Dimethyl-4-heptanol may be used in the preparation of the protected β-hydroxybutyrates. It may also be used as a hydrogen donor during the dynamic kinetic resolution (DKR) of various diols, monoprotected diols and the protected hydroxy aldehydes.
存储类别
10 - Combustible liquids
wgk
WGK 2
flash_point_f
150.8 °F - closed cup
flash_point_c
66 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
法规信息
新产品
此项目有
Mahn Joo Kim et al.
Current opinion in biotechnology, 13(6), 578-587 (2002-12-17)
The combination of enzyme and metal catalysis is described as a useful method for the synthesis of optically active compounds. A key feature of this new methodology is the use of metal catalysts for the in situ racemization of enzymatically
Lipase/ruthenium-catalyzed dynamic kinetic resolution of hydroxy acids, diols, and hydroxy aldehydes protected with a bulky group.
M J Kim et al.
The Journal of organic chemistry, 66(13), 4736-4738 (2001-06-26)
Dynamic kinetic resolution of secondary alcohols by enzyme?metal combinations in ionic liquid.
Kim MJ, et al.
Green Chemistry, 6(9), 471-474 (2004)
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