541524
5,5-二甲基-1,3,2-二氧磷杂环戊烷-2-酮
96%
别名:
2,2-二甲基丙烷-1,3-二醇环状膦酸酯, 亚磷酸氢新戊二醇, 新戊基烯亚磷酸盐, 环2,2-二甲基三亚甲基膦酸酯
产品名称
5,5-二甲基-1,3,2-二氧磷杂环戊烷-2-酮, 96%
InChI key
QHXZLTUNAVKFIT-UHFFFAOYSA-N
InChI
1S/C5H11O3P/c1-5(2)3-7-9(6)8-4-5/h9H,3-4H2,1-2H3
SMILES string
CC1(C)CO[PH](=O)OC1
assay
96%
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
mp
51-56 °C (lit.)
Application
用于以下反应的反应物：
- 钯（I）催化P（O）-H键的加成
- 高区域选择性改性的Pudovik加成反应
- 醋酸锰(III)介导的自由基反应
- 稳定的环DEMPO衍生物作为生物体系中立体选择性羟基自由基加合物形成的机械标记物
- 铜催化好氧氧化脱氢偶联反应
- 作为抗癌剂的双膦酸盐/磷酰胺
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
228.9 °F - closed cup
flash_point_c
109.4 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
J Fukal et al.
Physical chemistry chemical physics : PCCP, 21(19), 9924-9934 (2019-05-01)
Structural interpretation of the 31P NMR shifts measured in O,O-diethyl thiophosphate (PT), 5,5-dimethyl-2-mercapto-1,3,2-dioxaphosphorinane 2-oxide (cPT), diethylphosphate (P) and 5,5-dimethyl-2-hydroxy-1,3,2-dioxaphosphinane 2-oxide (cP) was obtained by means of theoretical calculations including the effects of geometry, molecular dynamics, and solvent, relativistic effects and
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持