产品名称
2-联苯硼酸, ≥95%
InChI
1S/C12H11BO2/c14-13(15)12-9-5-4-8-11(12)10-6-2-1-3-7-10/h1-9,14-15H
SMILES string
OB(O)c1ccccc1-c2ccccc2
InChI key
HYCYKHYFIWHGEX-UHFFFAOYSA-N
assay
≥95%
mp
167-172 °C (lit.)
functional group
phenyl
Application
用于与乙酸苄酯发生钯催化交叉偶联反应生成二芳基甲烷的底物。
Reactant involved in:
- Suzuki-Miyaura cross-coupling reactions with arylhalides, dibromovinyl precursors, alkenyl tosylates and mesylates, and quinoline carboxylates
- Intramolecular Friedel-Crafts alkylation for synthesis of chiral tetralins
- Hydroxylation to phenols
- Oxidative coupling iwth alkynes
Other Notes
含有不定量的酸酐。
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Dongxue Han et al.
Nature communications, 11(1), 5659-5659 (2020-11-11)
Chiral optical materials based on circularly polarized luminescence (CPL) have emerged rapidly due to their feasible applications in diverse fields of research. However, limited to the small luminescence dissymmetry factor (glum), real application examples have rarely been reported. Here, we
Chuei Wakasugi et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 26(24), 5449-5458 (2020-02-23)
Transition-metal complexes bearing biaryl-2,2'-diyl ligands tend to show intense luminescence. However, difficulties in synthesis have prevented their further functionalization and practical applications. Herein, a series of platinum(II) complexes bearing biaryl-2,2'-diyl ligands, which have never been prepared in air, were synthesized
Ryoichi Kuwano et al.
Chemical communications (Cambridge, England), (47), 5899-5901 (2005-12-01)
Benzylic acetates reacted with arylboronic acids in the presence of a DPEphos-[Pd(eta3-C3H5)Cl]2 catalyst when tert-amyl alcohol was used as a solvent, and the catalytic cross-couplings produced diarylmethanes in high yields (up to 94% isolated yield).
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