547824
三[N,N-双(三甲基甲硅烷基)酰胺]钆(III)
98%
别名:
Gadolinium bis(trimethylsilyl)amide, Gadolinium tris[bis(trimethylsilyl)amide]
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关于此项目
线性分子式:
Gd(N(Si(CH3)3)2)3
化学文摘社编号:
分子量:
638.40
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23
方案
98%
表单
solid
反应适用性
core: gadolinium
reagent type: catalyst
mp
67-90 °C (lit.)
SMILES字符串
C[Si](C)(C)N([Gd](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C
InChI
1S/3C6H18NSi2.Gd/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3
InChI key
LFWPRLGQJJEPDP-UHFFFAOYSA-N
一般描述
Atomic number of base material: 64 Gadolinium
应用
在很多不对称催化应用中，应当使用手套箱和 Schlenk 技术防止此稀土催化剂与空气和水分接触，因为这两个因素将对反应结果产生不利影响。用无水溶剂配制该催化剂溶液并立即使用。
警示用语：
Danger
危险声明
危险分类
Flam. Sol. 1 - Skin Corr. 1B - Water-react 2
补充剂危害
储存分类代码
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
闪点(°F)
36.0 °F - closed cup
闪点(°C)
2.2 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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