54913
β-羟基丙酮酸锂 水合物
≥97.0% (calc. based on dry substance, NT)
别名:
β-Hydroxypyruvic acid 锂盐 水合物, 3-Hydroxy-2-oxopropionic acid 锂盐, 3-羟基-2-氧代丙酸 锂盐
质量水平
方案
≥97.0% (calc. based on dry substance, NT)
杂质
~1 mol water
官能团
ketone
SMILES字符串
[Li+].O.OCC(=O)C([O-])=O
InChI
1S/C3H4O4.Li.H2O/c4-1-2(5)3(6)7;;/h4H,1H2,(H,6,7);;1H2/q;+1;/p-1
InChI key
YHTVWBANKNBEKJ-UHFFFAOYSA-M
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应用
- Chiral polyol synthesis catalyzed by a thermostable Transketolase immobilized on Layered Double Hydroxides in Ionic liquids：研究β-羟基丙酮酸锂在手性合成中的催化应用(Ali et al., 2015)。
其他说明
转羟乙醛酶的底物；光学纯 L-2-羟基醛类化合物的制备
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Vahab Ali et al.
The Biochemical journal, 375(Pt 3), 729-736 (2003-07-25)
Putative NADPH-dependent GDH (L-glycerate dehydrogenase) of the protozoan parasite Entamoeba histolytica (EhGDH) has been characterized. The EhGDH gene encodes a protein of 318 amino acids with a calculated isoelectric point of 6.29 and a molecular mass of 35.8 kDa. EhGDH
Chen Yang et al.
Journal of bacteriology, 190(5), 1773-1782 (2007-12-25)
Members of a novel glycerate-2-kinase (GK-II) family were tentatively identified in a broad range of species, including eukaryotes and archaea and many bacteria that lack a canonical enzyme of the GarK (GK-I) family. The recently reported three-dimensional structure of GK-II
Juhan Kim et al.
Proceedings of the National Academy of Sciences of the United States of America, 109(42), E2856-E2864 (2012-09-18)
Evolution or engineering of novel metabolic pathways can endow microbes with new abilities to degrade anthropogenic pollutants or synthesize valuable chemicals. Most studies of the evolution of new pathways have focused on the origins and quality of function of the
Ronald G Duggleby
Journal of enzyme inhibition and medicinal chemistry, 20(1), 1-4 (2005-05-18)
Acetohydroxyacid synthase (Ec 2.2.1.6) catalyses the thiamine diphosphate-dependent reaction between two molecules of pyruvate yielding 2-acetolactacte and CO2. The enzyme will also utilise hydroxypyruvate with a k(cat) value that is 12% of that observed with pyruvate. When hydroxypyruvate is the
Renwick C J Dobson et al.
Protein science : a publication of the Protein Society, 17(12), 2080-2090 (2008-09-13)
In recent years, dihydrodipicolinate synthase (DHDPS, E.C. 4.2.1.52) has received considerable attention from a mechanistic and structural viewpoint. DHDPS catalyzes the reaction of (S)-aspartate-beta-semialdehyde with pyruvate, which is bound via a Schiff base to a conserved active-site lysine (Lys161 in
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