54913
β-羟基丙酮酸锂 水合物
≥97.0% (calc. based on dry substance, NT)
别名:
β-Hydroxypyruvic acid 锂盐 水合物, 3-Hydroxy-2-oxopropionic acid 锂盐, 3-羟基-2-氧代丙酸 锂盐
质量水平
方案
≥97.0% (calc. based on dry substance, NT)
杂质
~1 mol water
官能团
ketone
SMILES字符串
[Li+].O.OCC(=O)C([O-])=O
InChI
1S/C3H4O4.Li.H2O/c4-1-2(5)3(6)7;;/h4H,1H2,(H,6,7);;1H2/q;+1;/p-1
InChI key
YHTVWBANKNBEKJ-UHFFFAOYSA-M
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应用
- Chiral polyol synthesis catalyzed by a thermostable Transketolase immobilized on Layered Double Hydroxides in Ionic liquids：研究β-羟基丙酮酸锂在手性合成中的催化应用(Ali et al., 2015)。
其他说明
转羟乙醛酶的底物；光学纯 L-2-羟基醛类化合物的制备
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
O N Solov'eva et al.
Biochemistry. Biokhimiia, 66(8), 932-936 (2001-09-22)
The interaction of transketolase ketosubstrates with the holoenzyme has been studied. On addition of ketosubstrates cleaving both irreversibly (hydroxypyruvate) and reversibly (xylulose 5-phosphate), identical changes in the CD spectrum at 300-360 nm are observed. The changes in this spectral region
Shweta Joshi et al.
Molecular and biochemical parasitology, 160(1), 32-41 (2008-05-06)
The pentose phosphate pathway (PPP) is an important metabolic pathway for yielding reducing power in the form of NADPH and production of pentose sugar needed for nucleic acid synthesis. Transketolase, the key enzyme of non-oxidative arm of PPP, plays a
S Matosevic et al.
Journal of biotechnology, 155(3), 320-329 (2011-08-03)
Complex molecules are synthesised via a number of multi-step reactions in living cells. In this work, we describe the development of a continuous flow immobilized enzyme microreactor platform for use in evaluation of multi-step bioconversion pathways demonstrating a de novo
Y. Kobori et al.
The Journal of Organic Chemistry, 57, 5899-5899 (1992)
Chao Gao et al.
Bioresource technology, 131, 552-554 (2013-02-19)
In this work, bio-oxidation of glycerate was introduced for the green production of hydroxypyruvate. Whole cells of Pseudomonas sp. XP-LM were confirmed to have a good ability to produce hydroxypyruvate from glycerate. Under the optimal conditions, Hydroxypyruvate of 98.6 mM
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