551996
(S)-(+)-2-苄氨基-1-苯乙醇
97%
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关于此项目
线性分子式:
C6H5CH2NHCH2CH(OH)C6H5
化学文摘社编号:
分子量:
227.30
MDL编号:
UNSPSC代码:
12352116
PubChem化学物质编号:
NACRES:
NA.22
方案
97%
旋光性
[α]20/D +57°, c = 1 in chloroform
mp
115-118 °C (lit.)
官能团
amine
hydroxyl
phenyl
SMILES字符串
O[C@H](CNCc1ccccc1)c2ccccc2
InChI
1S/C15H17NO/c17-15(14-9-5-2-6-10-14)12-16-11-13-7-3-1-4-8-13/h1-10,15-17H,11-12H2/t15-/m1/s1
InChI key
XAOCLQUZOIZSHV-OAHLLOKOSA-N
一般描述
(S)-2-Benzylamino-1-phenylethanol can be used as a starting material in the preparation of iron catalysts applicable in the oxidation of secondary alcohols and benzylic methylene groups.
应用
(S)-(+)-2-Benzylamino-1-phenylethanol can be used as an intermediate in the synthesis of aziridines using α-amino and α-amido ketones via asymmetric transfer hydrogenation reaction.
法律信息
经 Shasun Chemicals and Drugs Limited 授权，使用 Jacobsen HKR 技术制造。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Polydentate pyridyl ligands and the catalytic activity of their iron (II) complexes in oxidation reactions utilizing peroxides as the oxidants
Lenze M, et al.
J. Mol. Catal. A: Chem., 373, 161-171 (2013)
Enantioselective synthesis of β-hydroxy amines and aziridines using asymmetric transfer hydrogenation of α-amido ketones
Kawamoto A and Wills M
Tetrahedron Asymmetry, 11(16), 3257-3261 (2000)
Enantioselective synthesis of β-hydroxy amines and aziridines using asymmetric transfer hydrogenation of α-amino ketones
Kawamoto AM and Wills M
Journal of the Chemical Society. Perkin Transactions 1, 373(16), 1916-1928 (2001)
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