551996
(S)-(+)-2-苄氨基-1-苯乙醇
97%
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关于此项目
线性分子式:
C6H5CH2NHCH2CH(OH)C6H5
化学文摘社编号:
分子量:
227.30
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352116
MDL number:
Assay:
97%
InChI
1S/C15H17NO/c17-15(14-9-5-2-6-10-14)12-16-11-13-7-3-1-4-8-13/h1-10,15-17H,11-12H2/t15-/m1/s1
SMILES string
O[C@H](CNCc1ccccc1)c2ccccc2
InChI key
XAOCLQUZOIZSHV-OAHLLOKOSA-N
assay
97%
optical activity
[α]20/D +57°, c = 1 in chloroform
mp
115-118 °C (lit.)
functional group
amine, hydroxyl, phenyl
General description
(S)-2-Benzylamino-1-phenylethanol can be used as a starting material in the preparation of iron catalysts applicable in the oxidation of secondary alcohols and benzylic methylene groups.
Application
(S)-(+)-2-Benzylamino-1-phenylethanol can be used as an intermediate in the synthesis of aziridines using α-amino and α-amido ketones via asymmetric transfer hydrogenation reaction.
Legal Information
经 Shasun Chemicals and Drugs Limited 授权，使用 Jacobsen HKR 技术制造。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Enantioselective synthesis of β-hydroxy amines and aziridines using asymmetric transfer hydrogenation of α-amido ketones
Kawamoto A and Wills M
Tetrahedron Asymmetry, 11(16), 3257-3261 (2000)
Polydentate pyridyl ligands and the catalytic activity of their iron (II) complexes in oxidation reactions utilizing peroxides as the oxidants
Lenze M, et al.
J. Mol. Catal. A: Chem., 373, 161-171 (2013)
Enantioselective synthesis of β-hydroxy amines and aziridines using asymmetric transfer hydrogenation of α-amino ketones
Kawamoto AM and Wills M
Journal of the Chemical Society. Perkin Transactions 1, 373(16), 1916-1928 (2001)
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