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551996

(S)-(+)-2-苄氨基-1-苯乙醇

Name: (<I>S</I>)-(+)-2-苄氨基-1-苯乙醇
Brand: ALDRICH

97%

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关于此项目

线性分子式:

C₆H₅CH₂NHCH₂CH(OH)C₆H₅

化学文摘社编号:

51096-49-2

分子量:

227.30

NACRES:

NA.22

PubChem Substance ID:

24879244

UNSPSC Code:

12352116

MDL number:

MFCD03427123

Assay:

97%

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属性

assay

97%

optical activity

[α]20/D +57°, c = 1 in chloroform

mp

115-118 °C (lit.)

functional group

amine, hydroxyl, phenyl

SMILES string

O[C@H](CNCc1ccccc1)c2ccccc2

InChI

1S/C15H17NO/c17-15(14-9-5-2-6-10-14)12-16-11-13-7-3-1-4-8-13/h1-10,15-17H,11-12H2/t15-/m1/s1

InChI key

XAOCLQUZOIZSHV-OAHLLOKOSA-N

说明

General description

(S)-2-Benzylamino-1-phenylethanol can be used as a starting material in the preparation of iron catalysts applicable in the oxidation of secondary alcohols and benzylic methylene groups.

Application

(S)-(+)-2-Benzylamino-1-phenylethanol can be used as an intermediate in the synthesis of aziridines using α-amino and α-amido ketones via asymmetric transfer hydrogenation reaction.

Legal Information

经 Shasun Chemicals and Drugs Limited 授权，使用 Jacobsen HKR 技术制造。

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

05701BO

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Enantioselective synthesis of β-hydroxy amines and aziridines using asymmetric transfer hydrogenation of α-amino ketones

Kawamoto AM and Wills M

Journal of the Chemical Society. Perkin Transactions 1, 373(16), 1916-1928 (2001)

Polydentate pyridyl ligands and the catalytic activity of their iron (II) complexes in oxidation reactions utilizing peroxides as the oxidants

Lenze M, et al.

J. Mol. Catal. A: Chem., 373, 161-171 (2013)

Enantioselective synthesis of β-hydroxy amines and aziridines using asymmetric transfer hydrogenation of α-amido ketones

Kawamoto A and Wills M

Tetrahedron Asymmetry, 11(16), 3257-3261 (2000)

全球贸易项目编号

货号	GTIN
551996-1G	04061825934389