蒸汽密度
>1 (vs air)
方案
97%
折射率
n20/D 1.417 (lit.)
n20/D 1.4170 (lit.)
沸点
92 °C (lit.)
密度
0.712 g/mL at 25 °C (lit.)
官能团
allyl
SMILES字符串
CC(=C)CCC=C
InChI
1S/C7H12/c1-4-5-6-7(2)3/h4H,1-2,5-6H2,3H3
InChI key
SLQMKNPIYMOEGB-UHFFFAOYSA-N
正在寻找类似产品? 访问 产品对比指南
一般描述
2-Methyl-1,5-hexadiene on mercury-photosensitized irradiation, undergoes internal cycloaddition to afford 1-methylbicyclo[2.1.1]hexane (as major product). High-temperature pyrolysis of 2-methyl-1,5-hexadiene affords 1,5-hexadiene and 2,5-dimethyl-1,5-hexadiene. 2-Methyl-1,5-hexadiene undergoes stereoselective and regioselective reaction with dialkylaluminum chloride (Et2AlCl) and titanium alkoxide [Ti(OPr-i)4, a catalyst] followed by oxidation to afford the corresponding five-membered 3-alkylcycloalkyl methanol. 2-Methyl-1,5-hexadiene is formed as a major product during the condensation reaction between allyl chloride and methallyl chloride in the presence of magnesium.
警示用语：
Danger
危险分类
Carc. 1A - Flam. Liq. 2 - Muta. 1B - STOT RE 2
靶器官
Blood
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
10.4 °F - closed cup
闪点(°C)
-12 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Olefins and Diolefins from Allylic Chlorides.
Henne AL, et al.
Journal of the American Chemical Society, 63(12), 3474-3476 (1941)
Vapor-phase thermolyses of 3-hydroxy-1, 5-hexadienes. II. Effects of methyl substitution.
Viola A, et al.
Journal of the American Chemical Society, 89(14), 3462-3470 (1967)
Mercury (3P1) photosensitized internal cycloaddition reactions in 1, 4-, 1, 5-, and 1, 6-dienes.
Srinivasan R and Carlough KH.
Journal of the American Chemical Society, 89(19), 4932-4936 (1967)
Vapor-phase thermolyses of 3-hydroxy-1, 5-hexadienes. II. Effects of methyl substitution.
Negishi EI, et al.
Journal of the American Chemical Society, 116(18), 8404-8405 (1994)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持