561487
噻霉酮
97%
别名:
1,2-苯并异噻唑-3-酮, 1,2-苯并异噻唑酮, 2,3-二氢-1,2-苯并噻唑-3-酮, 3-羟基-1,2-苯并异噻唑, 苯并异噻唑啉-3-酮
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关于此项目
经验公式（希尔记法）:
C7H5NOS
化学文摘社编号:
分子量:
151.19
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
220-120-9
MDL number:
Assay:
97%
Form:
solid
InChI key
DMSMPAJRVJJAGA-UHFFFAOYSA-N
InChI
1S/C7H5NOS/c9-7-5-3-1-2-4-6(5)10-8-7/h1-4H,(H,8,9)
SMILES string
Oc1nsc2ccccc12
assay
97%
form
solid
mp
154-158 °C (lit.)
Quality Level
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General description
1,2-苯并异噻唑3（2H）-酮可以通过使2-巯基苯甲酸与二苯基磷酰基叠氮化物反应来合成。
Application
1,2-苯并异噻唑-3(2H)-酮可作为前体合成生物活性更高的1,2-苯并异噻唑啉-3-酮(BIT)。
Disclaimer
本品不可用作全球生物杀灭剂法规监管的生物杀灭剂，包括但不限于：美国联邦杀虫剂、杀菌剂和灭鼠剂法(US EPA′s Federal Insecticide Fungicide and Rodenticide Act)、欧盟生物杀灭剂法规(European Biocidal Products Regulation)、加拿大虫害管理监管机构(Canada’s Pest Management Regulatory Agency)、土耳其生物杀灭剂法规(Turkey’s Biocidal Products Regulation)、韩国生物杀灭剂法(Korea’s Consumer Chemical Products and Biocide Safety Management Act (K-BPR))等。
signalword
Danger
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1A
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
法规信息
农药列管产品
此项目有
Convenient Synthesis of 1, 2-Benzisothiazol-3 (2H)-ones by Cyclization Reaction
of Acyl Azide
of Acyl Azide
Chiyoda T, et al.
Synlett, 2000(10), 1427-1428 (2000)
William L Jorgensen et al.
Bioorganic & medicinal chemistry letters, 21(15), 4545-4549 (2011-07-02)
Substituted N-phenylbenzisothiazolones have been investigated as inhibitors of the tautomerase activity of the proinflammatory cytokine MIF (macrophage migration inhibitory factor). Numerous compounds were found to possess antagonist activity in the low micromolar range with the most potent being the 6-hydroxy
Kristiina Aalto-Korte et al.
Contact dermatitis, 57(6), 365-370 (2007-11-09)
Benzisothiazolinone is used as a slimicide in the manufacture of disposable powder-free polyvinyl chloride (PVC) gloves. We recently reported 6 patients from dentistry and health care probably sensitized to benzisothiazolinone in PVC gloves. The study aimed to investigate how widely
Alan Rolfe et al.
Journal of combinatorial chemistry, 11(4), 732-738 (2009-06-10)
A sequential three-component synthesis of functionalized benzisothiazoline-3-acetic acid 1,1-dioxides utilizing a domino Heck-aza-Michael pathway is reported. This one-pot procedure rapidly assembles functionalized benzylsulfonamides, which undergo a palladium-catalyzed, domino, Heck-aza-Michael transformation in an experimentally straightforward manner. This attractive protocol has been
D A Basketter et al.
Contact dermatitis, 40(3), 150-154 (1999-03-12)
Many of the chemicals in common use possess, to some degree, a capacity to cause skin sensitization. Consequently, it is important to conduct a thorough and accurate risk assessment when it can be anticipated that such chemicals are likely to
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