mp
610 °C (dec.) (lit.)
SMILES字符串
[Cs+].[Cs+].[O-]C([O-])=O
InChI
1S/CH2O3.2Cs/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2
InChI key
FJDQFPXHSGXQBY-UHFFFAOYSA-L
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应用
提高醇 O-烷基化的效率以生成碳酸烷基酯混合物。
Catalyst for:
Reagent for:
- Aerobic oxidation of primary alcohols and of arylalkanes to aryl ketones.†
- 1,4-addition reactions
Reagent for:
- Synthesis of phosphazene derivatives
- Constrictive binding interactions
- Intramolecular C-N cross coupling reactions
- Dehydrohalogenative polycondensation
法律信息
Cabot Performance Materials 的产品
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Repr. 2 - STOT RE 2 Oral
靶器官
Kidney,Adrenal gland,Testes
储存分类代码
13 - Non Combustible Solids
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Synthesis, 3617-3617 (2006)
Yeon Sil Park, et al
Tetrahedron Letters, 51, 3956-3959 (2010)
Aylin Uslu, et al
Inorgorganica Chimica Acta, 363, 3721-3726 (2010)
Xiao-Jin Wu, et al
Advanced Synthesis & Catalysis, 351, 3150-3156 (2009)
Qifeng Wang et al.
Journal of the American Chemical Society, 132(33), 11420-11421 (2010-08-06)
Dehydrohalogenative polycondensation of 2-bromo-3-hexylthiophene was successful with Herrmann's catalyst and tris(2-dimethylaminophenyl)phosphine as catalyst precursors, giving head-to-tail poly(3-hexylthiophene) (HT-P3HT) with high molecular weight (M(n) = 30,600, M(w)/M(n) = 1.60) and high regioregularity (98%) in almost quantitative yield (99%).
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