578932
N-烯丙基-N,N-双(三甲基甲硅烷基)胺
97%
别名:
(Prop-2-en-1-yl)bis(trimethylsilyl)amine, 1,1,1-Trimethyl-N-2-propen-1-yl-N-(trimethylsilyl)silanamine, 3-Bis(trimethylsilyl)amino-1-propene, Bis(trimethylsilyl)allylamine, N,N-Bis(trimethylsilyl)-2-propen-1-amine, N,N-Bis(trimethylsilyl)allylamine, N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silanamine
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关于此项目
线性分子式:
CH2=CHCH2NH[Si(CH3)3]2
化学文摘社编号:
分子量:
201.46
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
231-699-2
MDL number:
Quality Segment
assay
97%
form
liquid
refractive index
n20/D 1.440 (lit.)
bp
72 °C/15 mmHg (lit.)
density
0.816 g/mL at 25 °C (lit.)
functional group
amine
SMILES string
C[Si](C)(C)N(CC=C)[Si](C)(C)C
InChI
1S/C9H23NSi2/c1-8-9-10(11(2,3)4)12(5,6)7/h8H,1,9H2,2-7H3
InChI key
CVNCFZIIZGNVFD-UHFFFAOYSA-N
Application
N-Allyl-N,N-bis(trimethylsilyl)amine or N,N-bis(trimethylsilyl)prop-2-en-1-amine (AHMDS) can be used as a nucleophilic reagent to prepare:
AHMDS can also be used as a reagent in hydrosilylation and hydroboration reaction. It may be also used as an electrolyte additive.
- Complex bicyclic scaffolds by reacting with aryl aldehydes via imine formation followed by efficient multicomponent reactions.
- Dithiasuccinoyl (Dts) heterocycle by reacting with bisthiocarbamoyl chloride.
- Allyl selenide by reacting with aryl selenium salt in the presence of a ruthenium catalyst; Allyl selenide is utilized as a key intermediate in organic synthesis.
AHMDS can also be used as a reagent in hydrosilylation and hydroboration reaction. It may be also used as an electrolyte additive.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
109.0 °F - closed cup
flash_point_c
42.78 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter