594261
5-溴异喹啉
98%
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关于此项目
经验公式（希尔记法）:
C9H6BrN
化学文摘社编号:
分子量:
208.05
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
产品名称
5-溴异喹啉, 98%
InChI
1S/C9H6BrN/c10-9-3-1-2-7-6-11-5-4-8(7)9/h1-6H
SMILES string
Brc1cccc2cnccc12
InChI key
CYJZJGYYTFQQBY-UHFFFAOYSA-N
assay
98%
mp
83-87 °C (lit.)
functional group
bromo
Application
用于钯催化的氨甲基化和胺化反应的原料。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Qilong Shen et al.
Journal of the American Chemical Society, 128(31), 10028-10029 (2006-08-03)
A mild, palladium-catalyzed coupling of aryl halides with ammonia or lithium amide to form primary arylamines as the major product is described. These reactions occurred with excellent selectivity for formation of the primary arylamine over formation of the diarylamine (9.5:1
Gary A Molander et al.
Organic letters, 9(8), 1597-1600 (2007-03-21)
[reaction: see text] The Suzuki-Miyaura cross-coupling reaction of N,N-dialkylaminomethyltrifluoroborates with aryl halides allows the construction of an aminomethyl aryl linkage through a disconnection based on dissonant reactivity patterns. A variety of these aminomethyltrifluoroborate substrates were prepared in good to excellent
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